类水滑石复合氧化物催化分解n2o的实验分析-experimental analysis of catalytic decomposition of n2o by hydrotalcite-like compound oxides.docxVIP

下载本文档

1
0
约4.9万字
约 63页
2018-05-29 发布于上海
举报
版权申诉

类水滑石复合氧化物催化分解n2o的实验分析-experimental analysis of catalytic decomposition of n2o by hydrotalcite-like compound oxides.docx

1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
4、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
5、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
6、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
7、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

类水滑石复合氧化物催化分解n2o的实验分析-experimental analysis of catalytic decomposition of n2o by hydrotalcite-like compound oxides

AbstractGreenhouse gas emissions is a topic of global concern, nitrous oxide (N2O) become one of the hot subjects on environment because of their high global warming potential. In this work, we make hydrotalcite- like precursors Co-M-Al series and Co-M-Al-Ce series by coprecipitation, and prepare catalysts for catalytic decomposition of N 2O by high temperature calcination, on the xperimental research of catalytic decomposition of N2O, we achieved the following findings:The XRD and FTIR results showed that the series of Co-M-Al and Co-M-Al-Ce prepareed by coprecipitation except Co0Cu3-HT belongs to hydrotalcite precursors. The hydrotalcite- like precursors contain CeO2 characteristic diffraction peaks with Ce introduction. After calcination, the majority of hydrotalcite precursors form composite oxides and own spinel structure when the content of Co is high.Experimental study found that different series of catalysts have different catalytic decomposition temperature when N2O conversion rate were 50% and 90%. In the series ofCo-M-Al catalysts, the most active Co2.5Ni0.5 catalytics T50 and T90 were 417℃ and469℃. In the series of Co-M-Al-Ce catalysts, the most active Co2.5Ni0.5Ce0.05 catalysts T50 and T90 were 310℃ and 380℃. In the series of K / Co-M-Al-Ce catalysts, the most active 1.5% K/Co2.5N i0.5Ce0.05 catalytsts T50 and T90 were 310℃ and 380℃.the K /Co-M-Al-Ce series, the most active 1.5% K/Co2.5N i0.5Ce0.05 catalytsts T50 and T90 were 261℃ and 346℃. Thus, 1.5% K/Co2.5N i0.5Ce0.05 catalyst has better application prospect relative to other two series of catalysts.N i-containing catalysts by XPS characterization results showed that after the introdction of elements N i, chemical environment surrounding Co has be changeed, and Co electron transfer capability is improved, which may be the reason for the high activity of theCo2.5Ni0.5 catalyst; After the introdction of elements Ce, the metal oxide particles arereduced and the dispersion are increased, whi