锂离子电池正极材料lini0.5mn1.5o4的制备、改性与电化学性能分析-preparation, modification and electrochemical performance analysis of lini 0.5 mn 1.5 o4 as cathode material for lithium ion batteries.docxVIP

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锂离子电池正极材料lini0.5mn1.5o4的制备、改性与电化学性能分析-preparation, modification and electrochemical performance analysis of lini 0.5 mn 1.5 o4 as cathode material for lithium ion batteries.docx

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锂离子电池正极材料lini0.5mn1.5o4的制备、改性与电化学性能分析-preparation, modification and electrochemical performance analysis of lini 0.5 mn 1.5 o4 as cathode material for lithium ion batteries

Preparation and modification of LiNi0.5Mn1.5O4 electrode materials for lithium ion batteries and their electrochemical performanceAbstractThe demand for new lithium ion battery cathode materials has been increased with the wide use of lithium ion battery in daily life. In this paper, we carried out research work on the preparation and modification of high voltage LiNi0 .5Mn1.5O4 as cathode of lithium ion batteries.LiNi0 .5Mn1.5O4 was prepared with soluble salts of Li, Ni and Mn by a one-step co-precipitation method using (NH4)2CO3 as precipitant. The effect of synthesis temperature on the performance of LiNi0.5Mn1.5O4 electrode materials was investigated. The results of charge and discharge tests showed that the sample prepared at 850 oC exhibited optimum electrochemical results. The initial discharge capacity of the sample reached 126.1, 125.0, 120.0, 105.0 and 79.7 mAh g-1 at the rate of 0.1 C, 0.5 C, 1 C, 5 C and 10 C, respectively. And after 100 cycles it could retain 94% of its initial discharge capacity at the rate of 0.5 C.In addition, the LiNi0.5Mn1 .5O4 prepared by solid state method was doped with different amounts of cobalt. The results showed that LiNi 0.45Co0.1Mn1 .45O4 exhibited the best electrochemical performance. The initial discharge capac ity reached 116.7, 112.2, 110.8, 106.5 and 97.2 mAh g-1 at the rate of 0.1 C, 0.5 C, 1 C,5 C and 10 C, respectively. After 100 cycles it could retain 89.1% of its initial discharge capacity at the rate of 0.5 C.The electrochemical performance of a full lithium ion battery constructed ofLiNi0 .45Co0.1Mn1 .45O4 cathode and Li4Ti5O12 anode has been explored. The full lithium ion battery has a stable platform at the voltage of 3.2 V and delivers an initial discharge capacity of 104.4 mAh g-1 at 0.1 C based on LiNi0.45Co0.1Mn1.45O4. After 50 cycles, the discharge capacity retain s 50.6 mAh g-1.Key words: Lithium ion battery; Cathode material; LiNi0 .5Mn1.5O4 ; LiNi0 .45Co0.1Mn1 .45O4致谢本论文是在导师杨则恒教授的悉心指导和严格要