锂离子正极材料li2fesio4 li3v2po43的制备及电化学性能研究-preparation and electrochemical properties of li - ion cathode material li2 fe sio 4 li 3 v2 po 43.docxVIP

AbstractDeveloping cheap, sustainable and safe cathode materials is a prime target for large scale lithium batteries. With iron and silicon being among the most abundant and lowest-cost elements, Li2FeSiO4 cathode materials have been attracted significant attention. Another polyoxyanion Li3V2(PO4)3 cathode materials not only have goodsecurity, but also have higher Li+ ion diffusion coefficient than LiFePO4. Therefore,Li2FeSiO4 and Li3V2(PO4)3 positive materials have a good application prospect, but the two materials both have low electronic conductivity. In this paper, sol-gel method and carbon reduction method are combined for preparing Li2FeSiO4/C and Li3V2(PO4)3/C lithium-ion battery cathode materials. The morphology, crystal structures and the group situation are investigated by the scanning electron microscope (SEM), X-ray diffraction (XRD) and infrared spectroscopy (FI-IR), respectively. The electrochemical performances of them are characterized by the cyclic voltammograms (CV), galvanostatic measurements and exchange impedance analysis (EIS).Li2FeSiO4/C cathode materials were prepared by sol-gel method and carbon reduction method. The effect of the different way for adding carbon as a conductive phase, the complexing agent, the pH value, and calcining temperature on morphology and electrochemical properties of Li2FeSiO4/C were investigated. The results indicate that the right condition(pH = 6) for the solution with citric acid owned three of the carboxyl as complexing agent would complex the Fe2+ ion better. Adding sugar in theball mill process, and calcining at 700℃ for 10 h for preparing the Li2FeSiO4/Cmaterial, the surface evenly coated a layer of carbon as conductive agent, which can reduce the charge transfer impedance, improve the electrochemical performance with a specific capacity of 154.4 mAh g-1 at 0.1 C, and 142.5 mAh g-1 has been maintained after 20 cycles.The Li2Fe1?xMnxSiO4/C samples were suscessfully prepared by the same method above-mentione