lamg2ni9xyzcoxmnycuz系列储氢合金的制备 组成及其电化学性能研究-study on the preparation composition and electrochemical properties of lamg 2 ni9 xycoxmnycuz series hydrogen storage alloys.docxVIP
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lamg2ni9xyzcoxmnycuz系列储氢合金的制备 组成及其电化学性能研究-study on the preparation composition and electrochemical properties of lamg 2 ni9 xycoxmnycuz series hydrogen storage alloys
LaMg2Ni27C02.IMn21CUJ.5isLL!C03.whichhasthebestsyntheticelectrochemistryperformance.ThemainphaseofLaMg2NiL2C03.oMn13CUJ.5isLaNisandsomeLa4Cù3,whichhasthebestthecyclestability.ThemainphaseofbothL曲1Nì4.8CoL8Mn2ICuO.3andLaMg2Ni39Cù2IMn2JCuO.9isCo,whichhasthelowestmaximumdischargecapacityandtheworstcyclestabili纱,respectively.ηlepreliminaryconclusionisthatLL!C03phasecanenhancesthesyntheticelectrochemistryperformanceofthisseriesalloys,LaNisphasecanenhancesthecyclestabilityandCophasecanmakethesyntheticelectrochemistryperformanceworse.Keywordscoprecipitation-reduction-diffusionmethod;multielementsubstituted;AB3typehydrogenstoragealloys;componentanalysis;electrochemis町prope町m目录第-意绪论.......................................................….....……........….......…........…1.1储氢合金的理论基础…........………….........…·…………........…...............…….......2J.J.1储氨合金吸氢机理.......................….........………........…2J.J.2储氢合金的化学原理........................................…………….......….........…........…..2J.1.3储氢含金的电化学原理.................…........….........….........…..............…31.1.4储氢合金的晶体结构...................………….......……...............…....................…......41.2储氢含金的评价因素.........…………............................…...............….........……............51.3储氢合金的类型与性自Eu--…......……........…·……….................…................…61.3.1ABs型储氢合金................................................…......…........……61.3.2AB2型储氢合金(Ti、Zr系Laves相合金).........…………........…7I.3.3AB型储氢合金山系合金)…..............................…...............................…81.3.4A2B型储氨合金(Mg系储氢合金)................……............................……81.3.5{丰心立方固溶体型…………………………………………………………………………………....9l.3.6A民型储氢合金…………................……........……………............……..………….....91.4储氢合金的制备方法.................……...............…·………………….................................101.4.1感应炉熔炼法.........…........................…….............…....…...……....…..................101.4.2机械含金化(MA,MG)法....….........……...............................…101.4.3还原扩
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