二维纳米材料的自组装及组装体的性能分析-self - assembly of 2d nanomaterials and performance analysis of assemblies.docx

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二维纳米材料的自组装及组装体的性能分析-self - assembly of 2d nanomaterials and performance analysis of assemblies.docx

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二维纳米材料的自组装及组装体的性能分析-self - assembly of 2d nanomaterials and performance analysis of assemblies

anduniformplatinumparticles.Thecorrespondingplatinum-basedcatalystalsomanifestsstrongeranti-poisonability.(4)Two-dimensionalvermiculitenano-layerswithhighaspectratiowereobtainedthroughexfoliatingvermiculitecrystalsusingion-exchangemethod,andthesetwo-dimensionalnano-layerscanreadilystackintoflexiblevermiculitemembranewithuniforminterlayerspacings,andtheas-preparedmembranehashighthermalstability.Thesenano-scaledspacingscanworkasnanofluidicchannelsforiontransportation,andtheassemblyofthemembraneisinfacttheintegrationofhundredsofnanofluidicchannels.Inthisthesis,protontransportationthroughtheintegratednanofluidicchannelswasstudied,andtheconductancedatademonstratedthatprotontransportationinlowconcentrationconditionwasgovernedbythesurfacechargesonthevermiculitelayers.Keywords：two-dimensionalnano-material,graphene,grapheneoxide,vermiculite,self-assembly,layeredmaterial目录第一章绪论.............................................................................................................-1-1.1引言.................................................................................................................-1-1.1.1层状材料..................................................................................................-1-1.1.2层状材料与二维纳米材料的关系..........................................................-3-1.1.3典型的层状材料——石墨和粘土..........................................................-3-1.2石墨烯——最薄的二维纳米材料.................................................................-5-1.2.1结构..........................................................................................................-6-1.2.2性质..........................................................................................................-7-1.2.3制备..........................................................................................................-8-1.3氧化石墨烯——石墨烯的官能化衍生物...................................................-10-1.3.1制备及结构............................................................................................-10-1.3