二维有序金球腔阵列的构筑及拉曼光谱分析-construction of two-dimensional ordered gold ball cavity array and raman spectrum analysis.docxVIP
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二维有序金球腔阵列的构筑及拉曼光谱分析-construction of two-dimensional ordered gold ball cavity array and raman spectrum analysis
二维有序金属球腔阵列的构筑及拉曼光谱研究英文摘要Wemanagedtousethegoldcavityarraysasamicro-ornano-vessel.Thesurfaceofthegoldcavitieswasadsorbedwithcetyltrimethylammoniumbromide(CTAB)molecules.TheCTABmodifiedcavitiesarepositivelycharged.Bytakingadvantageoftheelectrostaticinteraction,wemayselectivelyassemblythenegativelychargedparticles,suchas4-MBAmodifiedAgnanoparticlesintothecavitiestofabricateaparticles-in-cavity(PIC)structure.Duetothedissociationoftheadsorbed4-MBAontheAgNPsandthenetchargesoftheCTABbilayerinthegoldcavitiesbeingassociatedwiththepHvalueofthemedia,theassemblyof4-MBAmodifiedAgNPsintotheCTABmodifiedgoldcavitieswouldstronglydependonthepHvalueofthemedia.ItisclearlythatthereisapHwindowfortheimmobilizationofthe4-MBAmodifiedAgNPsintotheCTABmodifiedgoldcavities.Keywords:Self-assembly;Goldcavityarray;SERS;pHwindow;4-MBA.WrittenbyZhuominGuSupervisedbyProf.QunZhouIII目录第一章绪论.............................................................................................................11.1拉曼光谱..................................................................................................11.2表面增强拉曼散射..................................................................................21.3SERS基底的制备61.4SERS技术的应用111.5本论文的设想及研究内容.....................................................................12参考文献.............................................................................................................14第二章二维金球腔阵列的构筑及表征....................................................................192.1前言........................................................................................................192.2实验部分................................................................................................202.3结果与讨论............................................................................................212.4小结.......................................................................................................26参考文献................................................................................
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