二氧化氯固体制剂及其母体材料环境安全性分析-environmental safety analysis of chlorine dioxide solid preparation and its parent materials.docxVIP
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                二氧化氯固体制剂及其母体材料环境安全性分析-environmental safety analysis of chlorine dioxide solid preparation and its parent materials
                    (1)在撞击感度测试时,12#试样在锤重5kg、落高0.15m的撞击条件下迅速变黄,而13#试样在同等条件下未变黄,并且在撞击条件改为锤重10kg、落高2m时13#试样仍未变黄。在摩擦感度测试时,12#试样在摆角(66±1)°、表压(2.45±0.07)Mpa条件下迅速变黄,而13#试样在同等条件下未变黄,且将摆角增大至(80±1)°时13#试样仍未变黄,说明二元片剂的机械安全性较高;(2)静电感度测试表明,二者对静电均不敏感;(3)由DSC测试结果可知,在0~160℃范围内,二元片剂热安全性能较高,但随着温度上升至300℃,二者的危险系数均上升,均有爆炸危险。最后对包装材料和贮运提出一些合理化建议。关键词:二氧化氯,固体制剂,安全性能,DSC,撞击感度,摩擦感度,静电感度StudyontheenvironmentalsafetyofChlorinedioxidesolidpreparationanditsbasematerialAbstractChlorinedioxideisanewinternationallyrecognizedgenerationofidealdisinfectantforitshighefficiency,broadspectrumandnoresiduecharacters.Inrecentyears,ithadbeenwidelyusedinthecountriesallovertheworld.Duetothelimitationsofliquidandgaseouschlorinedioxide,solidpreparationsofchlorinedioxidewerewidelyacceptedbecauseofitshighefficiency,stableandconvenientcharacteristics.Butforthemaincompositionofchlorinedioxidesolidpreparationweresodiumchlorate,sodiumchloriteandsolidacid,Sodiumchlorateandsodiumchloritewerebelongtothecategoryofdangerouschemicals,whichhadstrongoxidizingproperties.Inthestorageandtransportationprocess,fireandexplosionphenomenonoftenoccured,whichcausedseriousinfluenceonitssafeuse,therefore,theresearchontheenvironmentalsafetyofchlorinedioxideSolidpreparationanditsbasematerialwasurgentlyneeded.Thefirstresearchcontentswereasfollows:tostudytheenvironmentalsafetyperformanceofbasematerialsofsolidchlorinedioxidepreparations(sodiumchlorate,markedas0#;sodiumchlorite,markedas0#),mechanicalsensitivity,electrostaticsensitivityandthermalsafetyperformancetestswerecarriedoutbysomedevicessuchasthefrictionandimpactsensitivityinstrument,electricsparksensitivityinstrumentandDSCinstrument,thedopinginfluenceonmechanicalsensitivityandelectrostaticsensitivitywerealsostudied.Experimentalresultswereshownbelow:Accordingtotesttheeffectivecontentofsamplesundercertaintemperatureandhumidityfortenhours,theresearchresultsshowedthat:underthesettledenvironmentalcondition(thetemperaturewere15℃,20℃,25℃,therelativehumiditywere50%,70%,90%),0#and1#samplesappearedthephenomenaofmetamo
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