混凝吸附方法深度处理焦化废水研究 毕业论文.doc

混凝吸附方法深度处理焦化废水的研究 摘要 本文以焦化废水二级生化出水为研究对象，采用膨润土、改性双氰胺PAC、PAM作为基本材料，对焦化废水进行深度处理。本课题探讨了膨润土的量、氢氧化钙的量、双氰胺改性絮凝剂的用量、PAC和PAM对焦化废水COD和色度的影响。试验结果显示：膨润土具有较高的吸附性能，当膨润土添加量为3.3g/L、PAC添加量为1.98g/L、PAM添加量为0.132g/L时，COD去除率达到59.2%，脱色率达到90.3%；改性双氰胺絮凝剂对焦化废水的色度有极高的去除作用，脱色率可达到91%以上，但对焦化废水的COD去除效果不明显。通过正交试验，确定焦化废水深度处理的最佳反应条件为：膨润土3.96g/L，氢氧化钙0.297g/L，改性双氰胺3.96ml/L，PAC 1.98g/L，PAM 0.132g/L。经本方法处理后，焦化废水的COD从180mg/L降到63mg/L，色度从250降低至50以下，达到国家《污水综合排放标准》（GB8978-1996 一级标准）。 关键词：膨润土；改性双氰胺；焦化废水；COD；脱色 Study on Advanced Treatment of Coking Wastewater by Coagulation and Adsorption Abstract In this paper, montmorillonite, modified dicyandiamide, polyaluminium chloride and Polyacrylamide were selected as experimental materials for the advanced treatment of coking wastewater，and the effect of addition quantity of montmorillonite, Ca(OH)2, modified dicyandiamide, polyaluminium chloride and Polyacrylamide on the removal of COD and color were disscussed too. Results were as follows: montmorillonite exhibited high adsorption capacity. The removal rate of COD and color for coking wastewater were 59.2% and 90.3% respectively when the addition quantity of montmorillonite was 3.3g/L, polyaluminium chloride was 1.98g/L and Polyacrylamide was 0.132g/L. modified dicyandiamide showed high ability on color, but the removal of COD was not obvious. The optimal process conditions based on orthogonal experiment were: montmorillonite 3.96g/L, Ca(HO)2 0.198g/L, modified dicyandiamide 3.96ml/L, polyaluminium chloride 1.98g/L and Polyacrylamide 0.132g/L. The COD value of treated coking wastewater decreased to 63mg/L and color below 50 under optimal conditions, which reached I-class criteria specified in “Integrated Wastewater Discharge Standard” (GB 8978-1996). Key word: montmorillonite; Modified dicyandiamide; Coking wastewater；COD; chromaticity 1 绪论 1 1.1 引言 1 1.2 焦化废水的来源及特点 2 1.3 焦化废水的处理技术现状 3 1.4 焦化废水的深度处理技术 4 1.4.1 生物法 4 1.4.2 化学处理法 4 1.4.3 物理处理法 6 1.5 本研究的的目的及意义 7 2、实验材料及方法 7 2.1 实验材料 7 2.1.1焦化废水 7 2.2 实验原料及仪