改性壳聚糖磁性吸附剂合成 表征及在吸附重金属 染料方面应用-synthesis and characterization of modified chitosan magnetic adsorbent and its application in adsorption of heavy metal dyes.docxVIP

AbstractContaminantofheavymetalsandsyntheticdyesinwaterhasledtosortsofecologicalandenvironmentalproblems.Kindsofnovelmagneticadsorbentshavebeendevelopedtoremoveheavymetalsanddyes,whichshowedvariousadvantages,suchashighlyefficient,low?cost,simple,convenient,andeasytooperateinindustrialscaleetc.Magneticadsorbentsthatcontainnaturalpolysaccharidechitosanandmagneticnanoparticlesownsomepropertieslikehighefficiency,cheapness,andbiodegradabilityetc.,sothattheymightbepotentialcandidatesinremovalofheavymetalsanddyes.Inthisthesis,twokindsofmodifiedchitosanmagneticadsorbentsweredesignedandprepared,andtheircapabilitiesandmechanismforadsorptionoftoxicmetalionsandcationicdyeswerefurtherinvestigated.Experimentalmethodsandresultsareshownasfollows:Twokindsofnovelchitosanmagneticadsorbents,EDTAmodifiedchitosan/SiO2/Fe3O4magneticadsorbent(abbreviatedtoEDCMS)andtaurinemodifiedchitosan/Fe3O4magneticadsorbent(abbreviatedtoTCM),weresynthesizedviasurfacemodificationandcharacterizedbyXRD,FTIR,SEM,TGA,VSMetc.EDCMSshowedexcellentadsorptioncapacityforCu(II),Cd(II)andPb(II)ionsatpH≥2.AtpH5and25°C,themaximumadsorptioncapacitiesforCu(II),Cd(II)andPb(II)were0.699,0.596and0.563mmolg?1,respectively.Besides,itexhibitedgoodadsorptionabilityfortwokindsofcationicdyes,i.e.crystalviolet(CV)andmethyleneblue(MB),indyesolutionsofpHhigherthan5.AtpH7and25°C,themaximumadsorptioncapacitiesforCVandMBwere227.3and138.9mgg?1,respectively.Also,itshowedgoodreusabilityforboththeheavymetalionsandthecationicdyes.Inaddition,itwasabletoefficientlyremovetheheavymetalsinsometraditionalChinesemedicineextracts,suchasextractsofastragalusroot,angelicaandcompositeofastragalusrootandangelica,andatthesametime,theamountofthemainpharmacodynamiccompositioninangelicaextract,i.e.ferulaicacid,didnotsignificantlychangedbeforeandaftertheremovalofheavymetals.TCMalsoexhibitedexcellentadsorptioncapabilityandreusabilityforMB.AtpH5and9(25°C),itsmaximumadsorptioncapacitiesforMBwere202.4and380.3mgg?1,respectively.Keywords:Modifiedchitosan;Magnetic