改性壳聚糖吸附剂脱除烟气中汞的实验与机理分析-experimental and mechanism analysis of mercury removal from flue gas by modified chitosan adsorbent.docx

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改性壳聚糖吸附剂脱除烟气中汞的实验与机理分析-experimental and mechanism analysis of mercury removal from flue gas by modified chitosan adsorbent.docx

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改性壳聚糖吸附剂脱除烟气中汞的实验与机理分析-experimental and mechanism analysis of mercury removal from flue gas by modified chitosan adsorbent

thermalstabilityofCTSdecreasesaftermodifyingbyH2SO4,andpotassiumiodide,whileitcanbeincreasedgreatlywhenbentonitesupportedonthechitosan.XRDspectrashowthattheareaunderamorphousdecreasesaftermodification.Thisiscausedbythefactthatinter-andextra-molecularhydrogenbondsaredestroyedduetothepresenceofH2SO4.Furthermore,thepeakofI2isobservedintheiodineandH2SO4modifiedCTSsorbent,whichimpliestheoccurrenceoftheinteractionbetweenH2SO4,KIandchitosan.XPSanalysisrevealsthatnitrogenatomprovideselectronpair,andsulfuratominclinestoaccepttheelectron.Moreactivesites,suchasSandCl,canbeeasilyobtainedaftersilanizationinsilicon-modifiedCTSsorbent.Adsorptionexperimentsofvapor-phaseelementalmercury(Hg0)werestudiedusingthesesorbentsinalaboratory-scalefixed-bedreactorwithnitrogenasgassources.VM3000onlinemercuryanalyzerwasappliedtodetecttheinletandoutletHg0concentrations.TheresultsshowthattheparentCTShasnoeffectonHg0removal.Thecopper-templatedCTSsorbents,whichhavememoryfunctionforCu2+vacancy,canadsorbthemetalionorvapor-phasemetalwhichhassimilarradiusascopperion.ThesechangescanimprovetheHg0andHg2+captureefficiencygreatly.Forthesilicon-modifiedCTSsorbent,mercuryremovalefficiencyimproveswiththepresenceofO2.Fortheiodineorbromide-modifiedCTSsorbents,mercuryremovalefficiencyofCTSsorbentscouldbesignificantlypromotedwhenappropriateamountofH2SO4wasadded.Generally,theiodineandacidmodifiedsorbentsdemonstratehighermercurycaptureefficiencythanthatofbromineandacidmodifiedsorbents.Silver-modifiedB/CTSsorbentsexhibitsomewhatpoormercuryremovalefficiencyathigherreactiontemperature,whiletheyshowhighermercurycaptureperformanceatroomtemperature.TheresultsobtainedundersimulatedfluegasesshowthatpresenceofSO2hasnegativeeffectonHg0removal.SomehowpositiveeffectoccurswhenHClisadded.ForiodineandacidmodifiedB/CTSandsilver-modifiedB/CTSsorbents,bothH2OandNOcanenhancetheadsorptionofHg0.ComparedtoiodineandacidmodifiedB/CTSsorbents,silver-modifiedB/CTSsorbentsshowamoresignificantchangecausedbyH2OandNO.Accordingtothepossibleadsorp