高温cao基吸附剂循环捕获燃煤烟气co2实验分析-experimental analysis on cyclic capture of co2 from coal-fired flue gas by cao - based adsorbent at high temperature.docxVIP

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高温cao基吸附剂循环捕获燃煤烟气co2实验分析-experimental analysis on cyclic capture of co2 from coal-fired flue gas by cao - based adsorbent at high temperature.docx

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高温cao基吸附剂循环捕获燃煤烟气co2实验分析-experimental analysis on cyclic capture of co2 from coal-fired flue gas by cao - based adsorbent at high temperature

增加，改善了吸附剂的循环吸附性能。关键词：CO2钙基吸附剂前置体掺杂镁盐吸附剂水合法热处理AbstractTheincreasingconcentrationofCO2intheatmosphereduetofossilfuelburninghasbeenidentifiedasamajorcontributortoglobalwarming.Inthepredictablefuture,fossilfuelswillcontinuetobethedominantenergysource,whichmeansthatCO2willcontinuetobereleasedintotheatmosphere.Tomitigatetherelatedglobalclimatedeterioration,largescaleCO2captureandsequestration(CCS)hasbeenproposedandwidelystudied.Withefficientenergyrecovery,itiswellacceptedthatCaO-containingmaterialsaregoodcandidateabsorbentsforCO2captureduetotheirhighreactivityforCO2absorption,highCO2capacity,lowmaterialcost,and,importantly,theirhighcarbonationtemperature.Inthispaper,ascreeningofpotentialcalciumprecursorsfortheproductionofCaOsorbentsforCO2captureathightemperaturewasconducted.TheprecursorsstudiedincludeCaO,CaCO3,CaC2O4,CaAcandCa(NO3)2.CaAcexhibitedthebestcapacityforcapturingCO2withaconversionof87.21%atthefirstcycleandaconversionof53.69%atthe10thcycle.Wealsoreportthatthemethodofincorporatingtheinertmaterialshasacriticaleffectonthelong-termstabilityoftheCaO-basedabsorbent.AclassofstableMgO-dopedCaOabsorbentshavebeendevelopedusingmechanicalmixingofsmallMgOparticleswithCa(CH3COO)2followedbyhightemperaturecalcinations.MgOwasselectedbecauseofitshighstability,lackofCO2absorptionattheCaOreactiontemperature,andlackofreactionwithCaOorCaCO3undertheoperatingconditions.MgOnanoparticlescanbeeasilyproducedbythermaldecompositionofmanyMg-containingsalts.WeexaminewaterreactivationofsorbenttoimprovethereversibilityofmultipleCaO-CO2capturecycles.AfterreactivationthesorbenthadevenbettercharacteristicsforCO2capturethanthatoftheoriginalsorbent.PretreatmentofCaO-basedsorbentinaCO2atmosphereathightemperatureisinvestigatedforitseffectonCO2capture.Pretreatmentwasdoneinatubefurnaceatdifferenttemperaturesandfordifferentdurations.Theresultsobtainedshowedsignificantdecreaseofsorbentsurfaceareaafterpretreatment,buttheporesurfaceareaofpretreatedsorbentsamplesincreasedafterCO2cyclingandSEMimagesshowedtherea