膨胀石墨eg协同新型磷系膨胀阻燃环氧树脂的制备及阻燃性能研究.docxVIP

第29卷第3期高校化学工程学报No.3Vol.292015年6月JournalofChemicalEngineeringofChineseUniversitiesJune2015文章编号：1003-9015(2015)03-0690-07膨胀石墨(EG)协同新型磷系膨胀阻燃环氧树脂的制备及阻燃性能研究卢林刚1,陈英辉2,郭楠2,杨守生3(1. 中国人民武装警察部队学院科研部, 河北廊坊065000;2. 中国人民武装警察部队学院 研究生队, 河北廊坊065000;3. 中国人民武装警察部队学院 消防工程系, 河北廊坊065000)摘要：经六(4-DOPO羟甲基苯氧基)环三磷腈(DOPOMPC)和聚磷酸铵(APP)处理环氧树脂(EP)的基础上加入可膨胀石墨(EG)，制备新型膨胀阻燃环氧树脂复合材料(DOPOMPC/APP/EG/EP)。通过极限氧指数(LOI)、水平垂直燃烧(UL-94)、 锥形量热(CONE)、扫描电镜(SEM)等方法，研究了协效剂EG加入对复合材料阻燃性能和力学性能的影响。结果表明，适量EG与DOPOMPC/APP体系有良好的协同阻燃作用，并提高了环氧树脂复合材料力学性能。当DOPOMPC/APP/EG总添加量为22%(DOPOMPC/APP/EG的比例为5/5/1)，复合材料LOI值高达38.4%；热释放速率峰值(pk-HRR)、比消 光面积(av-SEA)、有效燃烧热平均值(av-EHC)和一氧化碳释放率平均值(av-CO)较纯EP(EP0)分别降低了81.8%，35.5%、 29.0%和33.3%；其拉伸强度、弯曲强度和冲击强度比EP1(10%DOPOMPC/10%APP/EP)体系分别提高了70.5%、1.5倍 和2.6倍。关键词：膨胀石墨；环氧树脂；膨胀阻燃剂；协同阻燃中图分类号：TQ314.248；文献标识码：ADOI：10.3969/j.issn.1003-9015.2015.03.028PreparationandPerformanceofExpandedGraphiteAddedPhosphorus IntumescentFlame-RetardantEpoxyResinsLU Lin-gang1,CHENYing-hui2,GUONan2,YANGShou-sheng3(1.DepartmentofScience andTechnology,ChinesePeoplesArmedPolice ForceAcademy, Langfang065000,China; 2.DepartmentofFire ProtectionEngineering,ChinesePeoplesArmedPoliceForceAcademy, Langfang065000,China; 3.GraduatesForces, ChinesePeoplesArmedPoliceForceAcademy, Langfang065000,China)Abstract: An intumescentflame retardant compositewas prepared byadding expandedgraphite(EG) in the 6(4-of DOPO hydroxymethyl phenoxy) cyclotriphosphazene (DOPOMPC) and polyphosphate (APP) treatedepoxyresin(EP)system.TheeffectofEGcontentonflameretardingpropertieswasstudiedbylimitedoxygenindex(LOI),UL-94,CONE,TGandSEM,andtheretardantmechanismwasdiscussed.Theresultsshowthatthisnewtypeofepoxyresincompositeshasbetterflameretardantperformance,lesssmokeandtoxicity,andenhanced mechanical properties. The limited oxygen index value could reach to 38.4% for the samplecontaining22%DOPOMPC/APP/EG（DOPOMPC/APP/EG5/5/1).TheCONEexperimentalresultsshowthatpk-HRR, av-SEA, av-EHC and av-CO values of the new composite reduced by 81.8%, 35.5%, 29.0% and 33.3