新型染料敏化剂应用于染料敏化太阳能电池的初步分析-preliminary analysis of application of new dye sensitizer in dye-sensitized solar cells.docxVIP

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新型染料敏化剂应用于染料敏化太阳能电池的初步分析-preliminary analysis of application of new dye sensitizer in dye-sensitized solar cells.docx

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新型染料敏化剂应用于染料敏化太阳能电池的初步分析-preliminary analysis of application of new dye sensitizer in dye-sensitized solar cells

AbstractDye-sensitized solar cells (DSSC) as a new-type solar cell have received extensive attentions due to their low production cost, easily fabricated properties, acceptably high efficiency and less environment pollution.So far the best conversion efficiency of DSSC has reached 12.3%, since the first report of 7.12% efficiency by Gr?tzel and co-workers in 1991. DSSC are now regarded as the third generation solar cells which are technically and economically credible alternative to the currently dominating silicon photovoltaic cells, although their efficiency less than the silicon solar cells. Researchers are working on improving their efficiency in recent years and made remarkable achievements. The high performance dyes are one of the most important factors.With the goal to further improve the performance of DSSC, this thesis focuses on synthesis of new sensitizer, coabsorber and cosensitizer based on changing the dye structures. The main points of the thesis are as following:New sensitizer ZW1, coadsorber ZW2 and cosensitizer ZW4 were designed and synthesized , according to the basic design principle of the high efficient dyes.After simply optimizing the TiO2 nanocrystalline film-thickness and electrolytes, DSSC devices with these new synthesized dyes were prepared.These cells J-V and IPCE spectra indicate that ZW1 and ZW2 are usefull to improve DSSC power-conversion efficiency (PCE).Key words：Solar cellsDye-sensitizedsensitizercoadsorbercosensitizer目录摘要 .................................................................................................................. IAbstract................................................................................................................II1绪论1.1前言 ............................................................................................................ 11.2太阳能电池的发展状况 ............................................................................ 42染料敏化太阳能电池工作原理2.1染料敏化太阳能电池的结构及原理 ....................................