液体分散靛蓝的制备及其染色性能分析-preparation and dyeing performance analysis of liquid disperse indigo.docxVIP

摘要牛仔布是由经向色纱和纬向白纱织成的一种经典服用织物，经纱染色常用的染 色方法有浆染联合染色、束状染色、螺旋式染色等，而靛蓝染料是最常用的染料。 目前商品粉状靛蓝染色常常出现色泽不够艳丽，色深不够，色光不纯，重现性差， 还原温度高、染化料使用量大等等弊端。本课题以粉状靛蓝为主要原料，加入特殊的分散体系，通过研磨制备出液体分 散靛蓝，分析了其分散和稳定性能，选择不同的还原剂和氢氧化钠浓度还原该液体 靛蓝，然后上染织物，通过对织物色光，K/S 值、摩擦色牢度等的测试和还原体系的 优化设计，得到了最优还原体系值。液体分散靛蓝采用木质素磺酸钠为分散剂，分散剂质量为染料用量的 5%，经过 4h 研磨而制得，质量浓度为 20%，该分散体系能在室温下放置 60 天而不变质，且离 心稳定性好。与粉状靛蓝比较，液体分散靛蓝研磨分散后颗粒直径变小，比表面积增大，颗 粒更均匀，更利于染色 ，且使用的染化料更低。经过优化设计后，通过回归分析和 显著性分析得出，保险粉和氢氧化钠浓度对染色织物的染色性能（L*、a*、b*、C*、 H°、皂煮前、后的 K/S）具有显著性影响，且符合线性回归方程。测得其最优解分 别为：1）液体靛蓝优化解，还原温度为 40℃，还原时间 46min，保险粉浓度 126g/L， 氢氧化钠浓度 98g/L；2）粉状靛蓝优化解，还原温度为 56℃,还原时间 26min，保险 粉浓度 165g/L，氢氧化钠浓度 108g/L；二者相比，液体靛蓝染化料使用量更低，织 物的上染率高，颜色深，液体分散靛蓝体系的 COD 值相对较低；而通过拉曼光谱和 织物的 K/S 的测试，再一次说明液体靛蓝织物的上染率更高，染色更深。关键词液体分散靛蓝；粒径；染色体系；还原体系；优化设计IAbstractDenim is a classic woven fabric, made up of warp dyed yarn and weft white yarn, the common used dyeing methods of warp have pulp dyeing joint, beam dyeing, spiral dyeing, etc., indigo dye is the most commonly used dyes. But the powdered indigo dyeing often appear poor gorgeous color, poor color depth, not pure color, poor reproducibility, reduction temperature high, huge dyestuff usage, and so on.This paper uses powdered indigo as the main raw material, added special dispersion system, and prepares liquid dispersed indigo by grinding, analyzed dispersion and stable performance, choosing different reducing agent and sodium hydroxide concentration reduction of the liquid indigo, then dyeing the fabric, tested the fabric color, K/S and friction fastness and optimized redox system, obtained the optimal value reduction system.Liquid dispersion indigo uses sodium lignin sulfonate as dispersant, dispersant quality was 5% of dye dosage, grinding 4 h, mass concentration was 20%, the decentralized system can place 60 days at room temperature without metamorphism, and the centrifugal stability is well.Compared with powdered indigo, liquid dispersed indigo grain diameter smaller, specific surface area increased, particles is more uniform, mor