ZK镁合金微弧氧化硅酸盐电解液的优化及膜层特性.docVIP

ZK60镁合金微弧氧化硅酸盐电解液的优化及膜层特性 第2O卷第10期 Vb1.2ONO.1O 中国有色金属 TheChineseJournalofNonferrousMetals 2010年10月 Oct.20lO 文章编号:1004.0609(2010)10.1868—08 ZK60镁合金微弧氧化硅酸盐电解液的 优化及膜层特性 芦笙,徐荣远,陈静,侯志丹,王泽鑫,汤莉 (1.江苏科技大学材料科学与工程学院,镇江212003;2.江苏科技大学机械工程学院,镇江212003) 摘要:在硅酸钠,氢氧化钠,四硼酸钠和柠檬酸钠组成的电解液中,采用交流脉冲电源对ZK60镁合金进行微 弧氧化,研究电解液组分对膜层的影响规律,并优化电解液配方.利用光学显微镜,扫描电镜(SEM),能谱分析 fEDS)和X射线衍射分析(XRD)等,研究膜层厚度,表面与截面的微观组织,通过静态腐蚀质量损失法和动电位 极化曲线法测试膜层在3.5%NaC1介质中的耐蚀性能.结果表明:各电解液组分浓度对成膜过程的电压变化,膜 层厚度和耐蚀性能的影响规律各不相同,并在不同的合适浓度下获得厚的膜层和较高的耐蚀性能.通过单变量实 验和正交实验优化电解液配方:60g/LNaSiO3+20g/LNaOH+25g/LNaB4O7+20g/LC6H5Na307,制备出的膜厚高 达164.89pan,结构均匀,致密,腐蚀速率极低,仅为ZK60镁合金空白试样的1.8%. 关键词:ZK60镁合金;微弧氧化;NaESrO3电解液;配方;膜层 中图分类号:TG174.453文献标志码:A Optimizationofsilicateelectrolyteformicro—arcoxidationand characteristicofcoatingfabricatedonZK60magnesiumalloy LUSheng,XURong—yuan,CHENJing2, HOUZhi.dan,WANGZe—xin,TANGLi r1.SchoolofMaterialsScienceandEngineering, JiangsuUniversityofScienceandTechnology,Zhenjiang212003,China; 2.SchoolofMechanicalEngineering,JiangsuUniversityofScienceandTechnology,Zhenjiang212003,China) Abstract:Themicro—arcoxidationprocesswasconductedonZK60MgalloyinanelectrolytecomposedofNaSiO3, Na0H,NaB4O7andC6H5Na3O7byACpulseelectricalSOUrCe.nlecoatingthicknessandmicrostructuralcharacteristics ofcoatingcross—sectionandsurfacewereinvestigatedbymearlsofOM.SEMcoupledwithEDSandXRD.111emass lossanddynamicpotentia1curvesweremeasUredina3.5%NaClsolutiontoevaluatethecoatingresistancetocorrosion. Theresultsrevealthatdifferentelementsoftheelectrolytedemonstratedifferenteffectsonprocessvoltage,coating thicknessandcorrosionresistance.Foranelementoftheelectrolyte,thereisusuallyasuitableconcentrationtoobtaina thickercoatingbutwhichdoesnotguaranteeabeRercorrosionresistance.Bymeansofsinglevariableando~hogonal tests,anoptimizedelectrolyrewithacompositionof60NaSiO3+20gmNaOH+25gmNaB407+20gmC6H5Na307 wasdeveloped.Thesamplepreparedwiththeoptimizedelectrolyteexhibitsgoodcorrosionpropertywithonly1.8%of corrosionrateofblanksampleduetoitsthicker(164.89m)anddense