预氧化—混凝—沉淀对铜绿微囊藻与soc复合污染的去除-removal of compound pollution of microcystis aeruginosa and soc by preoxidation - coagulation - precipitation.docxVIP

AbstractThecombinedpollutionisacommonphenomenoninwaterbodies,Becauseofjointeffectorinteractioneffectorprocesscouplingeffect,thecombinedpollutioncouldoccurredbetweenpollutants.Inthisstudy,aseriesofexperimentsforcombinedpollutionofMicrocystisaeruginosa-nitrobenzene(M.aeruginosa-NB)andMicrocystisaeruginosa-polychlorinatedbiphenyls(M.aeruginosa-PCBs).ThemutualeffectbetweenM.aeruginosaandNBorPCBs(syntheticorganiccompounds,SOC);theremovaleffectofthecombinedpollutionbycoagulation-precipitationandPre-oxidation-coagulation-precipitationwascarriedout.ResultsshowedthatM.aeruginosapresentedenrichmentabilityandexcellentdegradabilityforNB.InashorttimeafterM.aeruginosaandNBcontacted,M.aeruginosaachievedthestrongestenrichmentabilityforNB,thebioconcentrationfactors(BCF)was103.28；however,theenrichmentabilityforNBdeclinedsubsequently,7daysafterM.aeruginosaandNBcontacted,theBCFwas103.28.TheconcentrationofNBthatdegradedbyM.aeruginosaincreasedsuccessivelyaftertheycontacted,andthehigherinitialconcentrationofNB,thehigherdegradationratebyM.aeruginosa.Forexample,whentheconcentrationwas314.24μg/LofNB,after1dayand7days,thedegradationratewas7.23%、30.72%,respectively.Extracellularorganicmaterials(EOM)ofM.aeruginosacanincreasesolubilityofPCBs.M.aeruginosacanenrichPCBstoo,buttheenrichmentabilitywasrelatedtothechlorinatedextentofdiphenyl,thehigherchlorinatedextent,thestrongerenrichmentability.After24hoursthatM.aeruginosaandPCBscontacted,theBCFwas104.36forPCB28,and104.59forPCB138.RemovaleffectofM.aeruginosaandturbiditybycoagulation-precipitationwasverywell,theremovalratewasmornthan98%.TheremovalrateoftotalTrihalomathanesFormationPotential(THMFP)ofM.aeruginosa-NBpollutionbycoagulation-precipitationwasabout90%,mornthanM.aeruginosapollution.BecausethemajoritytotalTHMFPwasconstitutedbyM.aeruginosa,sototalTHMFPwasremovedwellwhenM.aeruginosaremovedbycoagulation-precipitation.OwingtotheNB,M.aeruginosageneratedandsecretedevenmoresolubleorganicmaterialsandcausedtheconcentrationofextracellularTHMFPtoincrease;