云母微粒改性聚酰胺纤维制备及其性能分析-preparation and performance analysis of mica particle modified polyamide fiber.docxVIP

AbstractPolyamide fibers are widely used in socks, underwear and other clothing fabrics because of its excellent abrasion resistance, good flexibility, nice response rates and high strength. People are increasingly demanding on the quality of the fabric with the improvement of peoples living standards. Multiple functions consumers combined with fashion, health, comfort increasingly are being increasingly favored by consumers. The fabric that own moisture breathable, soft and warm, cool and comfortable has become an important issue that public research institutes and many chemical fiber enterprises have researched and developed.In this paper, slice polyamide was used as matrix, self-prepared nano-mica filler was modifier, cool PA6 fibers were prepared. Several properties of PA6-Mica blend containing rheological properties, crystal properties and thermal properties were tested and analyzed through capillary rheometer, differential scanning calorimetry, thermal conductivity meter. The mechanical properties and resilience performance indicators of cool PA6 fibers were tested and analysed and The results showed that:Mica particles hinder the flow of PA6/Mica blends melt but do not change its flow type, PA6/Mica blends melt were pseudoplastic fluid shear thinning. Improving the mica particle content, an apparent viscosity of the blend melt increased and its melt flow properties decreased. Under the same shear rate, elevating temperature, PA6/Mica blends melt flow properties was improved. Blend melt viscous flow activation energy increased with the addition of mica particle, and the added amount of addition of the mica particles, the changing degree of the activation energy of viscous flow increased.Mica particles play a good part of heterogeneous nucleation on PA6. PA6 crystallized easier after adding in mica particles, whose crystallization rate increased. DSC test result showed mica particles can induce and generate γ polymorph. Thermal conductivity tests have shown tha