云母型含钒石煤工艺矿物学及选矿预富集工艺分析-technological mineralogy and beneficiation preconcentration process analysis of mica type vanadium-bearing stone coal.docx

钒云母一次浮选—尾矿再磨再选”流程，粗磨和再磨的磨矿细度分别为-0.074 mm占 63%和 85.6%，最终获得产率为 51.35%，V2O5 品位为 1.15%，回收率为 70.86% 的钒精矿。浸出试验表明，钒的品位是影响钒浸出率的重要因素，钒的品位越 高，浸出率越高。（4）焙烧对矿物浮选的影响主要表现在矿物组成及晶体结构的改变、矿浆 中离子浓度的增减和矿物表面性质的变化三个方面。石煤经焙烧脱炭，煤完全 分解，细粒的白云母和高岭石等粘土矿物脱除层间水和部分羟基，疏水性增强； 浮选矿浆中的 Mg2+、Ca2+、Ba2+及 Si4+的浓度增加，降低了捕收剂对方解石和白 云母的选择性；粗粒的石英和方解石等矿物表面粘附有微细粒的白云母和粘土 矿物，高温焙烧增强了矿粒之间的粘结力，浮选时疏水性增强的细粒优先吸附 在选择性降低的气泡上，使细粒和被细粒包裹的粗粒无选择的上浮进入精矿中， 钙钒分离困难，钒损失较大。关键词：含钒石煤；云母；工艺矿物学；选矿预富集IIAbstractVanadium-bearing stone coal is an important resource and widespread in China, the total reserve of it is abundant. However, because the properties of stone coal are complex, the vanadium grade and occurrence is generally low and multiple, current vanadium extraction technology is lack of pertinence. Meanwhile, the technology faces challenges in terms of large ore tonnage and high energy consumption, acid consumption and cost, low vanadium leaching rate, serious environmental pollution. The challenges showed above restrict the development of vanadium extraction industry. Contrapose the properties of vanadium-bearing stone coal, the paper took vanadium-bearing stone coal in Hubei province of China as research object and put forward a new process for pre-concentration of vanadium from stone coal by physical separation. Based on the mineralogical study of stone coal and its decarburizationsample in 700oC, the effects of pre-concentration of vanadium from stone coal bygravity separation and floatation were discussed and the best processes were ascertained. In the end, the influence on minerals in stone coal caused by decarburization was investigated. The main conclusions were as follows:The vanadium grade of high calcium mica-type stone coal was 0.71% and the grade of CaO was 6.26%. Vanadium existed in the lattice of muscovite, taking placeof aluminum in isomorphism. There were only V(Ⅲ) and V(Ⅳ) existed in muscovite.It was confirmed that the primary minerals ware quartz, coal, muscovite, pyrite and calcite; other minerals were feldspar,