SI-ATRP技术用于新型含氮螯合树脂的制备及其吸附功能研究.pdf

8．15 Abstract This was the resinanew atom highadsorption paper prepared capacitychelatingby technology transferradical resinwasusedas the polymerization．Thechloromethylation polystyrene macroinitiator．Threedifferentkindsof monomerswillbe tothesurface nitrogen grafted ofpolystyrene． The ofthethreenew resinswere in adsorptionproperties chelming investigateddetails，thesatisfactory resultshavebeenobtained．Theworkwasdoneasfo／lows： 1．Anew IDA resinwas viasurface—initiatedatomtransferradical high—capacitychelating synthesized ontothesurfaceof polymerization(SI-ATRP)method．Glycidylmethacrylate(GMA)wasgrafted the resinSI—ATRP the metal formedinthe chloromethyl polystyreneby using organiccompound as atroom IDA resinwas CuBr／2，2’一bipyridine(Bpy)systemcatalyst temperature．Thechelating Iminodiacetic the of surface synthesizedbygrafting acid(IDA)on polyglycidylmethacrylate resin．The resinwascharacterizedmeansof (PGMA)modifiedpolystyrenechelating by elementary evaluatedin to analysis，and detailsdetermineits and ofkinetics adsorptionpropertiesparameters the and amountofIDAonthesurfaceof resinwascalculatedto thermodynamics．The polystyrene be8．15