晶化调节剂对钛硅分子筛ts-1及膜催化性能的影响-effect of crystallization regulator on ts - 1 and membrane catalytic performance of titanium silicalite molecular sieve.docxVIP

prepared via seeding methods. The probe reaction of direct hydroxylation of benzene to phenol was used for testing the catalytic activities of TS-1 membranes, the results revealed that TS-1 membrane with ammonium carbonate as crystallization-mediating agent was possessed of remarkable catalytic performance.KEY WORDS：TS-1 zeolites, TS-1 membrane, crystallization-mediating agent, benznen, phenol, catalytic activity目录第一章 绪论 ..............................................................................................................................11.1 苯酚的生产、需求现状 .................................................................................................11.2 苯酚的生产方法 .............................................................................................................21.2.1 煤焦油提取法 ...........................................................................................................31.2.2 苯磺化法 ..................................................................................................................31.2.3 苯氯化法 ...................................................................................................................31.2.4 异丙苯氧化法(Hock Process)41.2.5 甲苯氧化法 ...............................................................................................................51.2.6 拉西法(氧氯化法) ....................................................................................................51.2.7 环己烷法 ...................................................................................................................61.2.8 苯直接氧化法 ...........................................................................................................61.3 钛硅分子筛与钛硅分子筛膜概述 ...............................................................................111.4 钛硅分子筛(TS-1)及膜的合成 121.4.1 钛硅分子筛(TS-1)的合成 121.4.2 钛硅分子筛膜的合成 ............................................................................................131.5 钛硅分子筛及膜的表征 ..............................................