双钙钛矿Srlt;,2gt;FeMoOlt;,6gt;的制备、表征及电磁功能研究.pdfVIP

Abstract Abstract The magnetoresistance materials Sr FeMoO with double perovskite structure and series 2 6 of A site doped compounds were successfully synthesized by Sol-Gel method and microwave method. X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and vibrating sample magnetometer (VSM) were used to analyze and characterize the phase structure, the size and morphology of particles, magnetic and electric properties of the samples. First, with cheap activated carbon for reducing agent, the sol-gel method was used to prepare the giant magnetoresistance materials Sr FeMoO , which is the double perovskite 2 6 oxide. The influence of process conditions on the structure and magnetic properties of the samples was investigated in detail and the appropriate conditions were determined. The as-synthesized sample is Sr FeMoO with tetragonal crystal structure and I4/mmm space 2 6 group, and unit cell parameter is a = 5.580Å, c = 7.882Å. The grain size is below 100nm. The Curie temperature is above room temperature and the saturation magnetization of the sample 2 is 13.59A·m /kg under 1T at room temperature. The room temperature magnetoresistance of the sample under 1T field is up to -10.02%. The sample exhibit typical semiconductor behavior and the conductive mechanism can be described by small polaron variable range hopping model. + + + 3+