香草基壳聚糖季铵盐的制备及其缓蚀性能研讨.pdfVIP

香草基壳聚糖季铵盐的制备及其缓蚀性能研究 关键词：壳聚糖；绿色缓蚀剂；极化曲线；电化学阻抗谱 II 万方数据 香草基壳聚糖季铵盐的制备及其缓蚀性能研究 Preparation and inhibition performance of the vanillyl-chitosan quaternary ammonium salts Abstract Chitosan is a kind of environment-friendly materials, which has the ability to adsorb the metals and also has a poor ability of dissolving. Chitosan can be modified to derivatives through chemical reactions such as Schiff base reaction, quaternization reaction, which can make it to be used as inhibitor for wider application to the field of corrosion protection. In order to enhance the protection capabilities to the Q235 steel in hydrochloric acid and the solubility in strong acid environment, chitosan, in this study, has been modified to N-vanillyl-chitosan(VCS) by Schiff base reaction, and then has been turned into N-vanillyl-O-2’-hydroxypropyltrimethylammonium chloride chitosan (VHTC) by quaternarization reaction. The structure of VHTC is characterized by using FT-IR, 1H-NMR, elemental analysis, conductance titration and other methods. -1 Additionally, the inhibition performance of VHTC on Q235 steel in 1 mol·L HCl solution is studied by the weight-loss methods, the polarization curves, the electrochemical impedance spectroscopy and the surface morphology analysis. Results of weight-loss methods show that VHTC