对甲酚催化氢化合成4-甲基环己酮.pptVIP

Oxidation is a process in which The O.S.of some element increa -ses and in which electrons appe -ar on the right side of a half- equation. Reduction is a process in which The O.S.of some element decreases and in which electrons appear on The left side of a half-equation. Example Expressing an oxidation-reduction reaction through half-equations and an overall equation.show the oxidation and reduction that occur,and write an overall ionic equation for the reaction of iron which hydrochloric acid solution to produce H2(g)and Fe2+(aq). Solution Oxidation: Fe(s) Fe2+(aq) + 2e- Reduction: 2H+(aq) + 2e- H2(g) Overall: Fe(s) + 2 H+(aq) Fe2+(aq) + H2(g) 5-5 Balancing Oxidation-Reduction Equations The Half-Reaction (Ion-Electron) Method The basic steps in this method of balancing a redox equation are as follows : ?Write and balance separate half-equations for oxidation and reduction. ?Adjust coefficients in the two half-equations so that the same number of electrons appears in each half-equation. ?Add together the two half-equations (canceling out electrons)to obtain the balanced overall equation. Balancing the Equation for a Redox Reaction in Acidic Solution. The reaction described by expression is used to determine the sulfite ion concentration present in wastewater from a papermaking plant. Write the balanced equation for this reaction in acidic solution SO32-(aq) + MnO4-(aq) SO42- (aq) + Mn2+(aq) Example Step 1. Solution Write skeleton half-equations based on the species undergoing oxidation and reduction. The O.S. of sulfur increases from +4 in SO32- to +6 in SO42-. The O.S. 0f Mn decreases from +7 in MnO4- to +2 in Mn2+.The skeleton half-equations are SO3 2-(aq) SO42-(aq) MnO4-(aq) Mn2+(aq) St