含稀土三元配合物聚离子液体制备及其发光性能研究.doc

分类号： 密级： U D C： 编号： 河北工业大学硕士学位论文 含稀土三元配合物的聚离子液体的制备及其发光性能研究 论 文 作 者： 王冬月 学 生 类 别： 全日制 学 科 门 类： 工学硕士 学 科 专 业： 化学工艺 指 导 教 师： 李焕荣 职 称： 教授  Dissertation Submitted to Hebei University of Technology for The Master Degree of Chemical Technology PREPARATION AND LUMINESCENCE PROPERTIES OF POLY (IONIC LIQUID) CONTAINING TERNARY LANTHANIDE COMPLEXES by Wang Dongyue Supervisor: Prof. Li Huanrong May 2014    摘 要 离子液体被称为“设计”溶剂，通过将各种功能化基团嫁接到阴阳离子上制备新型离子液体，。三联吡啶功能基团具有很强的σ给电子能力，可以和多种金属离子形成稳定的配合物，而稀土因其具有特殊的电子结构在发光与光学材料中的应用。本论文离子液体及几种稀土配合物，将两者结合起来制备发光材料 合成了功能化离子液体TerpyVim[Br]和聚离子液体。 以-噻吩三氟丙酮(TTA)作为有机配体，与稀土离子Eu3+、Nd3+、Er3+合成稀土有机配合物Eu(TTA)3·2H2O、Nd(TTA)3·2H2O、Er(TTA)3·2H2O。 聚离子液体与稀土配合物Eu(TTA)3·2H2O、Nd(TTA)3·2H2O、Er(TTA)3·2H2O制备出新型的发光材料，荧光光谱、红外光谱、热重分析对其性能进行了Eu(TTA)3·2H2O的发光材料在紫外激发下能发射出明亮的红光，而含有Nd(TTA)3·2H2O、Er(TTA)3·2H2O 关键词：聚离子液体、三联吡啶、稀土配合物、荧光发光 ABSTRACT Ionic liquid (IL) is known as designer solvent. Task-specific ionic liquids can be applied to many fields by grafting various functional groups to the cations or anions part. Terpyridine functional group has strong σ-electron-donating ability to form complexes with various metal ions, lanthanide ions are attractive luminescent properties because of their special electronic structure. In this paper, we synthesized terpyridine functionalized poly(ionic liquid) and several binary lanthanide complexes, terpyridine can form luminescent materials upon complexing with lanthanide complexes. Ionic liquid monomer Terpy-Vim[Br] and the poly (ionic liquid) were successfully synthesized by us, which were characterized by NMR. Binary lanthanide complexes Eu(TTA)3·2H2O,Nd(TTA)3·2H2O,Er(TTA)3·2H2O were synthesized by complexing 2-thenoyltrifluoroacet(TTA) with Eu3+, Nd3+,Er3+ ions . Novel luminescent materials were synthesized by coordinating poly(ionic liquid) and binary lanthanide complexes. The obtained materials