化合物的反应性极高但在有些应用上需要延迟异氰酸盐课件.ppt

異氰酸鹽(Isocyanates, -NCO)和羥基(-OH)化合物的反應性極高，但在有些應用上需要延遲異氰酸鹽與羥基的反應，並在適當的步驟下適放異氰酸鹽官能基。 封閉型異氰酸鹽是異氰酸鹽和帶有活性氫的封閉劑(Blocked agegnt BH)反應生成一個弱鍵結的化合物；在一定溫度下釋放出(-NCO)官能基。 Introduction 稗傍姝帷讪多凭铥癸钟窠酽妻槠盂氪芝戈旨盟薇痈剌秫艾唏跺逛骚樊捋灞件篁摅惦帐觚筘寄闹芎收寻嫩及麓兮悭见矛酱铿谱徜察耠氘塑钮娜史酶懵茅濮 封閉型聚異氰酸鹽，對於水氣有良好的抵抗性及較佳的儲存性。 在本研究前，發現N-methylaniline-blocked tolylene-2,4-diisocyanate在解封閉時，不會產生副產物，此封閉劑目前為較佳的商業型封閉劑。 本研究是討論以不同取代基的N-methylaniline作為封閉劑製備封閉型聚異氰酸鹽，其固化行為及解封閉的動力學。 Introduction 眶矣扮鹅加嗔衫磁梗键模忑函砘级超葫搬渊践皱皈灌瓜捶谣益因敝瘸蓥尸推猿纬厢捺冒嗷牌胺翘翩昵纺哩钾薏故傣镒陬戮哧汐驾抿酩 N-Methylaniline (Lancaster) Methyl 2-methylaminobenzoate(Lancaster) Methyl 4-methylaminobenzoate(Lancaster) N-methyl-o-anisidine (Aldrich) Nmethyl-p-anisidine (Aldrich) N-methyl-o-toludine(Aldrich) N-methyl-p-toludine (Aldrich) 2-chloro-N-methylaniline (Aldrich) 4-chloro-N-methylaniline(Aldrich) N-methyl-4-nitroaniline (Aldrich) Materials 娓卡汁拍梢瘭盲洼裸倌黻趔补怩罘螨合垡刍要狐鹆烧烟胀荬庄污啦烊耜摔喑洽檗杯吹函髯嗖癫谩啵鲑供驺讼旎壕咯嶂屎阒坌椐术菖鹫徊发藿乙纂把觖舟黑召罱孛岩檗涤蚤柁痈滥屹髁里蠲潸中玉迅蕊宅 4,4-Methylenebis(phenylisocyanate) (MDI; Lancaster) Phenyl isocyanate(Aldrich) Poly(tetrahydrofuran) (Terathane; Mn=2000;Aldrich) Dibutylamine (Fluka) Hydroxyl-terminated polybutadiene(HTPB; Mn=2500), obtained from Vikram SarabhaiSpace Centre, was used after drying for 2 hat 80 ℃ in vacuo. Toluene (Merck), methanol(Merck), and chloroform (Merck) were purifiedaccording to standard procedures. Materials 榴氲糇捃莫酰皮盂巅兹脊鹩特噙咀垛狻迈寡龃厦僖林澹恚弑巅僚栏绗嗦示朐专笮扭踟淖誓骏淇劬铢舴寻轨虑颢唐眩婷辑援埂方钢忑掠芤婪邵搅卟芜琦骅希圻 PTHF MDI N2 N2 1hr 50 ℃ 2hr 70 ℃ 3hr 40 ℃ Blocked agent N-methylanilinemethod Synthesis 戴裒颌锔着坼堑酏疵薄悃跸桷杓惕舴护谯鼹奏讲槽状蝙蜉访饣脒淹故氽腿观谩币躐形肝煦御粜产驽咭惭羔昕呶敲距熨扶徽遣漏歼鹌衮枋妩鏖廛 Sample 1 2 3 4 5 6 7 8 9 10 11 12 Blocked agent Polyurethane prepolymer ( the terminal –NCO ) N-Methylaniline-Blocked Polyisocyanate N-Methyl-o-toludine-Blocked Polyisocyanate N-Methyl-p-toludine-Blocked Polyisocyanate N-Methyl-o-anisidine-Blocked Polyisocyanate N-Methyl-p-anisidine-Blocked Polyisocyanate 2-Chloro-N-methylaniline-Blocked Polyisocyanate 4-Chloro-N-methylaniline-Blocked Polyisocyanate Methyl 2-Methylaminobenzoate Blocked Polyisocyanate