义务教育7-4-1.pptVIP

The reactivity of the dienophile is increased if one or more electron-withdrawing groups are attached to its sp2 carbons A Molecular Orbital Description of the Diels–Alder Reaction Let’s focus on the HOMO and the LUMO of the reactants Stereochemistry of the Diels–Alder Reaction The reaction is a syn addition The Diels–Alder reaction is stereospecific The configuration of the reactants is maintained The reaction is concerted Alkynes are hydrocarbons that contain a carbon-carbon triple bond. a C≡C bond results from the overlap of two sp-hybridized carbon atoms and consists of one sp-spσbon