义务教育7-4-4.pptVIP

Summary and Key Words The chemistry of alkenes is dominated by addition reactions of electrophiles. When HX reacts with an alkene, Markovnikovs rule predicts that the hydrogen will add to the carbon that has fewer alkyl substituents and the X group will add to the carbon that has more alkyl substituents. Many electrophiles besides HX add to alkenes. Thus, Br2 and Cl2 add to give 1,2-dihalide addition products having anti stereochemistry. Addition of H2O (hydration) takes place on reaction of the alkene with aqueous acid, and addition of H2 (hydrogenation) occurs in the presence of a metal cat