义务教育7-7-2.pptVIP

Problem 7.I4. Rank the following compounds in order of their expected reactivity toward SN2 reaction: CH3I, CH3F, CH3Br. SN1 reactions can occur only when stable carbocation intermediates are formed. The more stable the carbocation intermediate, the faster the SN1 reaction. E1 eliminations begin with the same unimolecular dissociation we saw in the SN1 reaction, but the dissociation is followed by loss of H+ from the intermediate carbocation rather than by substitution. In fact, the E1 and SN1 reactions normally occur in competition whenever an alkyl halide is treated in a hydrox