Gas Chromatography - River Dell Regional School District …气相色谱-河戴尔区域学区….pptVIP

下载本文档

1
0
约2.3千字
约 9页
2018-06-24 发布于四川
举报
版权申诉

Gas Chromatography - River Dell Regional School District …气相色谱-河戴尔区域学区….ppt

1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
4、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
5、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
6、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
7、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

Gas Chromatography - River Dell Regional School District …气相色谱-河戴尔区域学区…

GCMS: gas chromatography and mass spectrometry in Forensic Science Applications What does the GCMS do? Separates complex mixtures of chemicals found in substances found at crime scene Quantifies the amount of each chemical present in a sample, compared to a standard part of database Identifies chemicals – determines the unique chemical composition and structure-its fingerprint Compared to a standard fingerprint Sample: mixture of volatile liquids (~1?L) Gas Chromatography Gas Chromatogram 0 5 10 15 20 Time (minutes) Abundance A B C D E Gas Chromatograph Gas Chromatograph Data System or Recorder Carrier Gas Supply Oven Capillary Column Injection Port Detector 194 67 109 55 82 42 165 136 94 40 60 80 100 120 140 160 180 200 Abundance Mass (amu) Mass Spectrum N C C N H C O C O N N C H C 3 H C 3 H Mass Spectrometer Mass Spectrometry Typical sample: isolated compound (~1 nanogram) Ion Source Mass Analyzer Ion Detector Inlet Data System Vacuum Pumps Sample Introduction Data Output Mass Spectrometer ~70 Volts + _ + _ e- e- e- + + + + + + _ Electron Collector (Trap) Repeller Extraction Plate Filament to Analyzer Inlet Electrons Neutral Molecules Positive Ions Electron Impact Ionization Source ion trajectory not in register (too heavy) Ion Source Detector ion trajectory not in register (too light) ion trajectory in register S N Magnetic Sector Mass Analyzer Electromagnet Detector Ion Source + _ _ DC and AC Voltages Quadrupole Ion Filter resonant ion non-resonant ion + * Overview of what a GC can do. ~ microliter injection volume is example only - sould not be construed as definitive * Block diagram of GC. * Horizontal axis (mis)labeled as mass rather than m/z so as to not to confuse them at first. Special molecule for Seattle. nanogram amount is an example only - should not be construed as definitive. * Block diagram of mass spectrometer. * EI source * * * Overview of what a GC can do. ~ microliter injection volume is example only - sould not be constru