硼化物硬质材料的高温高压合成与表征.pptVIP

报告内容 Structure of B60 Nano-structure of B60-Base Composite Fracture toughness Cutting test B6O-TiB2 超硬复合材料 * 贺端威 四川大学原子与分子物理研究所 高压科学与技术实验室 第３届中国金刚石相关材料及应用学术研讨会 2009年7月，大连 硼化物硬质材料的高温高压合成与表征 * 超硬材料在结构上的一般规律 B6O超硬材料及复合材料 ReB2,WB的高压合成、烧结及其表征 结语 Indenting methods Vickers hardness: HV = 1854.4 P/d2 (GPa) P: applied load (N) d: diagonal of the square-based diamond pyramid of the Vickers indenter (?m) Knoop hardness: HK = 14229 P/l2 d: long dagonal of the rhombus-based diamond pyramid of the Knoop indenter “Superhard” means materials with a Vickers hardness, Hv, exceeds 40 GPa. Definition for “superhard” conditions potential candidates : a three-dimensional covalent network short atomic bonds highly directional bonding a high density of valence electrons (7.05×1029 electrons/m3) What makes diamond, cBN special? Design of novel superhard materials Diamond is the hardest material known to mankind Vickers hardness (indentation): HV =70~100 GPa　 Graphite lowest hardness in Mohs scale (scratching) C-hexagonal ring layered structure Diamond High P-T Limitations: *Low thermal stability *React with ferrous metals during high-speed cutting sp2 bond sp3 bond B N c-BN c-BN is the second hardest material in industrial applications! Hardness: HV = 45~50 GPa thermal stability: 1100oC in air improved oxidation resistance high-speed cutting of steels sp2 bond sp3 bond High-P High-T Synthesis High-P High-T Cubic boron nitride 目前，金刚石和立方氮化硼是已成功应用在工业领域的两种超硬材料。 Herve′ Hubert* Chem. Mater. 10, 1998 16B + (1 + z)B2O3 = 3B6O + zB2O3 (atmospheric 1300oC ) HTHP synthesize can get better crystallized boron suboxide! B60超硬复合材料 Single B6 O crystal over 100 μm in size , synthesized at 5GPa and 2100 ℃, Using B crystalline boron lump with B2 O3 Powder. Duanwei He, et al.,J.Maer.Res., 17 2002 HV= 45 GPa Kic=4.5MPam1/2 Duanwei He, et al., Appl.Phys.Lett.,81 2002 Compression curves of boron suboxide from lattice parameters measured at 0?, 54.7?,