模拟泥沙海水冲刷环境下C钢的腐蚀电化学行为_雒娅楠.docVIP

——————————————————————————————————————————————— 模拟泥沙海水冲刷环境下3C钢的腐蚀电化学行为_雒娅楠 第42卷 第10期 2009年10月 天 津 大 学 学 报 Journal of Tianjin University Vol.42 No.10Oct. 2009 模拟泥沙海水冲刷环境下3C钢的腐蚀电化学行为 雒娅楠1，宋诗哲1,2，武 杰3，李 森1 (1. 天津大学材料科学与工程学院，天津 300072；2. 金属腐蚀与防护国家重点实验室，沈阳 110016； 3. 国家海洋局天津海水淡化与综合利用研究所，天津 300192) 摘 要：建立了实验室模拟海水冲刷腐蚀测试系统，采用极化阻力和电化学阻抗谱(EIS)等测试技术，研究了模拟实海流速冲刷环境下3C钢的腐蚀电化学行为以及流速和泥沙含量对3C钢腐蚀行为的影响．结果表明：在模拟实海流速 泥沙质量分数≤1.50‰时，3C钢在无泥沙和含泥沙海水中的EIS特征都为单一容抗弧；腐???电位随着流速≤0.80m/s、 的增加而升高，极化阻力则随流速的增加而减小，说明流速的增加加速了3C钢的腐蚀；泥沙含量的增加增大了表面冲 C钢的腐蚀速率略有增大． 刷作用，导致3 关键词：海水腐蚀；冲刷腐蚀；电化学阻抗谱(EIS)；极化阻力 中图分类号：TG172.5 文献标志码：A 文章编号：0493-2137(2009)10-0872-05 Corrosion Electrochemical Behavior of 3C Steel Under Simulated Erosion-Corrosion Condition by Seawater Containing Sediment LUO Ya-nan1，SONG Shi-zhe1,2，WU Jie3，LI Sen1 (1. School of Materials Science and Engineering，Tianjin University，Tianjin 300072，China； 2. State Key Laboratory for Corrosion and Protection of Metals，Shenyang 110016，China； 3. Institute of Seawater Desalination and Multipurpose Utilization，State Oceanic Administration(Tianjin)， Tianjin 300192，China) Abstract：A simulated erosion-corrosion test system has been set up，and the corrosion electrochemical behavior of 3 C steel and the influence of velocity and different concentrations of sediment on the corrosion behavior have been studied under the simulated condition of erosion-corrosion using polarization resistance and electrochemical impedance spectroscopy (EIS) C steel has only one capacitive reactance arc in both clear measurements. The results show that，as its EIS characteristics，3 seawater and seawater containing sediment when the simulated velocity is less than 0.80m/s and mass fraction of sediment is less than 1.50‰. With the increase of velocity of seawater，corrosion potential of 3C steel rises and polarization resistance C steel decreases，which indicates that the increase of velo