Vibrational spectroscopy振动光谱.pptVIP

Vibrational spectroscopy Surface Infrared spectroscopy Background Reflection Phase shift , electric field, intensity of p-polarized light as a function of incidence angle from a metal surface Adsorbate covered surface Surface selection rule Surface IR spectra of adsorbed molecules Peak width and intensity Instrumentation: RAIRS Instrumentation: MIR IR IR finger print Modes of vibration IR spectra of CO on Pd(100) IRRAS spectra Diffuse reflectance IR spectra High Resolution Electron Energy Loss Spectroscopy Scattering mechanism Impact scattering Peak positions for different adsorption states Instrumentation Examples: CO on W(100) Interaction ions with solid Atomic and nuclear collision Ion scattering spectroscopy Ion trajectroy Blocking, shadowing, and channeling effect Scattering cross section Quantitative analysis Stopping power and depth resolution Energy spectrum Channeling and blocking Surface peaks Energy distribution of sputtered species Sputtering yield: ion energy dependence Sputtering yield: dependence on element Sputtering yield: angle dependence Secondary Ion Mass Spectrometry (SIMS) SIMS modes Instrumentation Mass spectrometer Example Imaging SIMS Thermal desorption spectroscopyTemperature programmed desorpion Analysis of TPD Zero-order desorption kinetics First-order desorption kinetics n =1 Second order desorption kinetics n=2 Fractional order desorption kinetics Effect of pre-exponential factor k0 =1011 ~1015 1/sec Determination of activation barrier Ed varies 1/cosq Drop at grazing incidence angle Ion beam S+ Sensitive to top most layers Chemical composition Structural informations Very high sensitivity Imaging: 100~1000nm Depth profiling: 5nm Ion yield depends on surface concentration and sputtering yield Organic anlaysis: m/z = 5000~40,000 Matrix effect: secondary ionization mechanism Destructive: implantation, mixing, sputtering, ion beam induced surface chemistry, radiation induced atomic redistribution Mass detect sputtered species (ne