扫描隧道显微镜诱导金属表面有机分子多层膜发光研究-单分子科学专业论文.docx

ABSTRACTWith the rapid development of electronic information industry, the photoelectron materials and devices were all stepping into sub-wavelength nanoscale, and the nanoscale photoelectronics was born. It combined photoelectron technology and nano-technology, aiming to the interactions between electron and photon in nanoscale. One recently hot topic in nanoscale photoelectronics is nanoplasmonics. In this thesis, we would mainly discuss the investigation of coupling between electron and photon, surface plasmon and molecular dipole in sub-wavelength scale by Scanning tunneling microscope induced luminescence(STML) technology.Scanning tunneling microscope induced luminescence was based on that the tip’s highly localized tunneling current could excite photon emission by inelastic tunneling process. By the highly efficient collection and detection of photons, we could investigate the informations of photons from tunneling junction. It could reveal the electron-photon transitions in sub-wavelength tunneling junction with ultra-highspatial、time and energy resolution by STML technology. It would be helpful for us tocomprehend the transfer and combination of carriers、the energy transition and transfer in nanoscale.In chapter one, we introduced the background of both STML and nanoplasmonics. Inside this chapter, we would lay emphasis on the introduction to particular advantages of STML technology, when it was applied into nanoplasmonics. By the perfect combination between STML and nanoplasmonics, we were aiming to give clear physical pictures of couplings between electron and phonon, electron and photon, photon and nano-enviroment, plasmon and molecular dipole, etc in nanoscale, and finally to get the precise control of quantum system’s photon state.In chapter two, we investigated the STML of multi-layer porphyrin (TPP) molecules on metal substrate. Firstly, we prepared the atomic flat metal surface by sputtering and annealing in ultra-high vacuum. Then porphyrin