zn0.98co0.02opbzr0.52ti0.48o3异质结的制备及其磁性能分析-preparation and magnetic properties analysis of zn 0.98 co 0.02 op bzr 0.52 ti 0.48 o3 heterojunction.docx

AbstractIn this thesis, Zn0.98Co0.02O diluted magnetic semiconductor thin films were prepared by pulsed laser deposition (PLD), and their ferromagnetism origins were investigated. Then, Zn0.98Co0.02O/PbZr0.52Ti0.48O3 heterostructures were fabricated by PLD, and their ferromagnetism modulations under electric-field were discussed. The main research contents and the obtained results are summarized as follows:Preparation and ferromagnetism of Zn0.98Co0.02O thin filmsZn0.98Co0.02O thin films were prepared on Si (100) substrates under 450, 550 and 650 oC by PLD. The chemical compositions, magnetic properties and fine structures of the prepared films were characterized by X-ray diffraction (XRD), magnetic force microscopy (MFM), superconducting quantum interference device (SQUID), and extended X-ray absorption fine structure (EXAFS). The origin of ferromagnetism in Zn0.98Co0.02O thin films was also discussed. The MFM results show that there is no magnetic purity in the prepared films. The M-H curves indicate all prepared thin films exhibit room temperature ferromagnetism, and the saturated magnetization decreases with the increment of the substrate temperature. The EXAFS studies show that Co ions exist as substitutional Co2+ in the Zn0.98Co0.02O thin films when the substratetemperature is lower than 650 oC and then evolve into a secondary phase of Co3O4 when thesubstrate temperature is higher than 650 oC. In addition, the intrinsic ferromagnetism of Zn0.98Co0.02O thin films is explained by bound magnetic polarons (BMPs) model.Ferromagnetism of Zn0.98Co0.02O films prepared on Zn0.97Al0.03O buffer layerZn0.98Co0.02O films were prepared on Zn0.97Al0.03O buffer layer under 450, 550, and 650 oC by PLD. The resistance of Zn0.97Al0.03O buffer layer was characterized to be about 155 Ω from I-V curves by scanning probe microscopy. MFM measurements show there is no obvious magnetic impurities. SQUID results indicate that the ferromagnetism of Zn0.98Co0.02O films can be enhanced by