十字花科属植物籽的热解液化研究-热能工程专业论文.docxVIP

at 5~15 ℃ lower than before, and iron powder has a great influence on rapeseedcompared with other seeds; the main DTG peak of orychophragmus violaceus seed occurs at 6 ℃ higher than before, which iron powder could hinder its decomposition.The Coats-Redfern, Ozawa and Kissinger methods determine the kinetics parameters on thermal degradation, the results show: an apparent activation energy E of 35~55 kJ/mol is obtained for the selected seeds by Coats-Redfern method, in the presence of iron powder, E of seeds of field pennycress, lepidium apetalum and brassica campestris obviously decreases, especially rapeseed, the decreased degree isthe largest; E of orychophragmus violaceus seed increases a little；E of 110~150kJ/mol is obtained by Ozawa and Kissinger methods.We carried out fast pyrolysis of pennycress seeds in a fluidized-bed reactor in a quartz sand medium fluidized with nitrogen, with pyrolysis oil collected at acondensation，and at the pyrolysis temperature of 500℃, not only can high-carbon,high-energy liquid fuel intermediates of pyrolysis oil be produced but also these liquids are low-oxygen, low water content, neutral acidity. In the present of a catalyst Na2CO3(1 wt%), viscosity index of oil can be reduce by 30%, improving the pyrolytic oil quality.KEY WORDS: Biodiesel, Field pennycress, Pyrolysis characteristics, Model, Pyrolytic oil目录目 录 ...................................................................................................................................1第一章 绪论 .......................................................................................................................11.1 生物柴油概述 ......................................................................................................11.1.1 生物柴油的优缺点及实际应用问题 .....................................................11.1.2 国内外生物柴油的工业发展现状 .........................................................31.2 生物柴油制备方法和原料选择.........................................................................