部分草酸盐工艺制备pmn-pt铁电陶瓷-preparation of pmn - pt ferroelectric ceramics by partial oxalate process.docxVIP

ABSTRACTRelaxor-basedferroelectricceramics(1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3((1-x)PMN-xPT,PMN-PT)exhibitexcellentelectricalandelectro-opticalproperties,whichmakethempromisingapplicationsinmultilayerceramiccapacitors,piezoelectricactuatorsandtransducers,andopticaldevices.Inthisthesis(1-x)PMN-xPT(x=0.2-0.4)relaxor-basedferroelectricceramicswithperovskitestructurewerepreparedbythepartialoxalateroute.Theinfluencesofrawmaterialsselection,synthesistechnicsofprecursors,calcinationtemperatureandthecontentofPbTiO3(PT)onthephasestructure,microstructuremorphologyandelectricalpropertiesofthesynthesizedPMN-PTceramicswerestudiedsystematically.Theinfluencesofdirectcurrent(d.c.)biasvoltageandheattreatmenttemperatureonelectricalpropertieswerealsoresearched.X-raydiffraction(XRD)characterizationandelectricalpropertiesmeasurementsconfirmthatpureperovskite0.69PMN-0.31PTceramicswithexcellentelectricalpropertiescanbepreparedbyusingPb(Ac)2?3H2Oasrawmaterialviathepartialoxalateroutemethod.Thesynthesized0.80PMN-0.20PTpowderscalcinedat750℃exhibitratherpureperovskitestructure,littlegrainsize,ratherwell-distributionandlessconglomerationconfirmedbyXRDmeasurement,LaserParticleSizeAnalyzer,SEMobservationandspecificsurfaceareameasurement.Pureperovskite0.69PMN-0.31PTceramicscanbepreparedbyusingthe1100℃calcinedmixturesofthecolumbiteprecursorMgNb2O6andTiO2,whichexhibituniformmicrostructuremorphology,highrelativedensityandexcellentelectricalproperties.XRDstructureanalysisandelectricalpropertiesmeasurementsconfirmthatapparentcompositioninducedstructuralphasetransitionexistsinthePMN-PTceramicspreparedbythepartialoxalateroute.WiththeincreaseofthePTcontent,thephasestructureofthePMN-PTceramicschangesgraduallyfromrhombohedralferroelectricphase,acrossthemorphotropicphaseboundary(MPB)formedbythecoexistenceofrhombohedralandtetragonalferroelectricphases,andtotetragonalferroelectricphase.ThedielectricresponsecharacteralsochangesfromdiffusedferroelectricphaseIItransition(FPT)ofrhombohedralrelaxorferroelectricstofirst-o