吡啶2356四甲酸桥联的稀土金属多核配合物的合成 结构与性质研究-study on the synthesis structure and properties of pyridine 2356 tetracarboxylic acid bridged polynuclear complexes of rare earth metals.docxVIP

ABSTRACTIn recent years，the design and synthesis of metal organic frameworks (MOFs) with pyridine multicarboxylic acids have attracted much attention due to their interesting optical，electrical and magnetic properties. Pyridinetetracarboxylic acidhas more coordination sites than pyridinedicarboxylic acids and pyritrinedicarboxylic acids，therefore they can form high-dimensional frameworks as multiple bridged organic ligand . The high coordination numbers of rare earth metal ions may cause也difficulty in controlling the synthetic reactions and thereby the structures of the complexes.4ηle self-assembly of pyridine幽2，3，5，6 tetracarboxylic acid ( pdtc) w?th rareearth metal salts under hydrothermal conditions at 1600 gave two novel coordinationpolymers，{K[Nd(pdtc)(H20)]H20}n (l)， {K2[Dy(pdtc)(H20)]22H20}n(功， with Ni(ll) salts under hydrothermal conditions at 130 0 gave one coordination polymer ，{Nh(Hpdtc)2(bpY)24H20}n( 匀，whichwerecharacterizedbyIRspectrum， thermogravimetric (丁G) analysis，UV absorption spectrum and single-crystal X-ray dif1仕action.Complexes (1) and (2) were almost identical s阳cture and three-dimentional (3D) polymers. Both Complexes cηsta lized in orthorhombic with P2t2t2t space group. Each metal ion(Nd(III)，Dy(III)) were eight-coordinated and connected with four pdt沪by chelating and bridging modes. Main group metal potassium ion had coordination with pdtc 牛 in Complexes (1) and (2) 创 well ，which were 7-coordinated， 8.coordinated，respectively. Both Complexes showed Three-dimensional structuresvia brigding metal ions among one-dimentional zig亿ag chain. 3D supramolecular framework had hydrogen-bonds. Complex (3) crystallized in the monoclinic with‘P2l1Cspacegroup， andwere3Dsupramolecularframework.Pyridine-刀，5，6-tetracarboxylic acid pdtc) didnt completely deprotona饨， the use4ofthe small molecule ligands 4，4-bipyridine caused two different coordination modes-.of the Ni(II)，they both were six幽coordinated ，Octah