掺钴的klt2gtnblt4gtolt11gt的制备及光催化性能研究-preparation and photocatalytic properties of cobalt-doped klt 2 gtn blt 4 gto lt 11 gt.docxVIP

摘 摘 要染料废水的处理是一个具有重大实用价值的研究课题。染料废水是主要有害工 业废水之一，具有成分复杂、色度高、排放量大、毒性大、可生化性差等特点，染 料废水的处理是废水处理中的难题。光催化氧化技术处理有机废水是一个具有价值 的课题，该方法具有高效、节能、无二次污染等优点。本文采用固相法合成了KzNb40l。 和掺Co的K2Nb4011，研究了Co掺杂对K2Nb4011降解酸性红G溶液的光催化活性的影响。X射线衍射(XRD)分析表明，固相法合成的K2Nb40Il和掺C010％～15％的具 K2Nb4011有钨青铜(TB)型结构，掺Co样品中生成了少量的CoNb206，。扫描电镜 (SEM)测试表明，样品的颗粒大小分布不均，一般分白于500．800nm，并有轻度 团聚。利用自行设计的反应器，研究了掺Co的K2Nb4011对酸性红G模拟染料废水的 处理，取得了较好的降解效果。掺10％一15％Co的KzNb4011光催化性能均强于 K2Nb4011，当酸性红G浓度为50mg／L时，K2NbaOll对其降解两小时后的降解率可 达93％，而掺C015％的K2Nb4011可达到94．5％，K2Nb4011和CoNb206复合效应可能对 光催化性能的改善起主要作用。实验还表明，光催化剂的煅烧时问、煅烧温度、用 量、反应物的仞始浓度、pH等因素对光催化降解效率部有明显的影响。本实验条件下，催化剂的最佳合成条件是900℃1-煅烧6小时；兰{酸性红G浓度为50rag／L时， 催化剂的最佳投加量为1玑；当溶液在偏酸或偏碱条件下的降解率较高，且酸性条 件下比碱性条件下好。对掺co的K2Nb。01l悬浮体系的动力学研究表明，本实验条件下，催化剂对酸性红G的降解是一级反应，可以用L-H动力学方程描述。 本文利用紫外一可见光谱扫描，红外光谱等分析方法，探讨了酸性红G的降解机理。研究表明，酸性红G的降解主要是含co的K2Nb4011对其的光催化降解，而并 非吸附作用，但酸性红G自身也存在少量的光降解。关键词：钨青铜型；Co掺杂；光催化；酸性红G：降解AbstractDyeAbstractDye wastewater is an important source of harmful industry wastewater．The compositions of dye wastewater arc：very complicate，toxic and mostly nonbiodegradable and also resistant to destruction by physico—chemical treatment methods．Photocatalyticoxidation technology is an attractive method for treating wastewater,which is of high efficiency,energy saving and non—second contamination．In this paper,K2Nb40ll and Co-doped K2Nb4011 were prepared by solid··phase reaction and their photocatalyticactivities were evaluated by the photodegradation of acid red G on the catalysts．The results of X—ray diffraction(XRD)confirmed the crystal structure of K2Nb4011 and Co—doped(10-15 wt％)K2Nb40ll belong to tungsten·bronze(TB)type structure．CoNb206 was found in the Co—doped samples．The distribution of the particle sizes ofK2Nb4011 powders is form 500 to 800nm．The photocatalytic degradation results of acid red G by K2Nb40ll and Co·doped K2Nb4011 show that the photocatalytic activities of Co—doped(10-15 wt％)K2Nb40ll are better than KzNb4011．1 When the concentration of acid red G solution was 50m∥L thedegradatio