掺稀土la3nd3eu3gd3纳米成像材料的制备及其光学性能研究-preparation and optical properties of rare earth doped la 3n d3 eu 3g d 3 nano imaging materials.docxVIP

万方数据万方数据AbstractImaging technology plays a crucial role in the fields of molecular biology, cytology and clinical diagnosis. Imaging materials with superior properties can enhance the contrast and the resolution of the image. As a result, sophisticated images can be presented and more biological information can be obtained.The applications of traditional organic fluorescent dyes are limited due to its poor photochemical stability, broad absorption and emission bands, photobleaching and photolysis. Meanwhile, photolytic products often have a lethal effect on the organism. Besides, the fluorescent semiconductor nanocrystals are extensively studied in recent years. Howerer, its applications are still subject to some restrictions because of the poor chemical stability and toxicity. In contrast, the rare earth nanomaterials with unique optical, electrical, magnetic properties and low biological toxicity, have broad application prospects in biological imaging technology.Based on the previous study, a series of rare earth nanomaterials with different size, morphology and fluorescence properties were synthesized by hydrothermal method. The structures, morphologies and fluorescence properties of these nanomaterials are further characterized and analyzed. Moreover, the possible mechanism were investigated. By the use of water-soluble polymers as surface modification agents, functional groups are connected to the surface of nanoparticles. As a result, water-soluble nanoparticles with near infrared-to-near infrared fluorescence were obtained.This thesis consists of five parts: The first chapter includes a review of the preparation methods, research hotspots and application progress of rare earth nano-contrast materials. And the research purpose of this paper, as well as the main contents are described. In the second chapter, Gd2O3: Eu3+ nanorods were prepared by the method of solvothermal-calcination. The effect on the morphology of the reaction time, the pH value and calcinati