掺杂的尖晶石型limn,2o,4正极材料的制备和电化学性能的研究-preparation and electrochemical properties of doped spinel limn, 2o, 4 cathode materials.docxVIP

华中科技大学硕士学位论文摘华中科技大学硕士学位论文摘 要f锂离子电池是上世纪90年代初爿‘发展起来的一种高能量的二次电池。}If于它同传 统的二次电池相比，具有电压高、比能量高、工作温度范围宽、安全性能好、贮存和循 环寿命长以及环保等优点，已经丌始逐步取代一些传统的化学电源，在电子设备尤其是 一些小型和便携式电子设备上得到了广泛的应用。它将成为二十一世纪化学电源的主流。r)本文利用溶胶一凝胶法和固相法分别制备掺杂镧和镍的锂离子电池正极材料尖晶石 型LiM。Mn2．。04(M=La、Ni)，并利用X衍射、循环伏安、充放电测试、交流阻抗等手段 刈‘其进行了研究。／研究结果表明以cH3COOLi和Mn(CH3COO)2为原料用溶胶一凝胶法合成的掺杂La 的LiLao 005Mnl．99504的币极材料掺杂离子分布均匀，XRD数据表明该材料有着良好的尖 晶石结构。充放电测试表明LiLa0．005Mnl 99504有117mAh／g的初始容量和优异的循环性能。交流阻抗表明LiLa0005Mnl．99504有着较小的电荷传递阻抗。，卜用固相法制备掺杂镍的尖晶石锂锰『F极材料LiNi。Mn2．、04(x=0．05，0．I，0．2)。XRD数 据表明当掺杂量较小的时候，材料有着良好的尖晶石结构，当x=0．2时，其材料中有杂 质帽。充放电测试表明掺杂镍后，材料的初始容量都降低。其中LiNio osMn·8504有 104mAh／g初始容量和比较优异的循环性。循环伏安测试表明，随着掺杂镍的量的升高， 使得尖晶石品格结构区域无序化，两步氧化还原过程变得不明显。＼掺杂改性是提高LiMn204的循环性能的有效手段，随着研究的深入，一定可以在合成工艺和改善材料性能方面取得更大的进展。乒关键词：锂离子电池：尖品石型LiMn204：掺等)(讵极材料华中科技大学硕士学位论文ABSTRACT华中科技大学硕士学位论文ABSTRACTLithium—ion battery iS a high—energy secondary battery that has developed since the early 90’S last century．Compared to traditional secondary battery,it has many advantages such as， high voltage，high capacity,wide working temperature range，good security，long using lifetime and no pollution．It has gradually substituted traditional chemical power source and。has been used for specially small and portable electronic devices．It would be the mostpopular chemical power source．In the paper,the doped La and Ni cathode material spinel LiMxMn2。xG‰(Ⅺ=h、Ni)oflithium ion battery was prepared by sol-gel method and solid state method．Their crystalline type and electrochemical properties were measured by XRD，cyclic voltammetry，charge-- discharge test and AC impedance．The results revealed that the doped ions distributed uniforrnly in the doped La negative material spinel毛i毛韵oosMnl 99504 that Was prepared by sol·gel method with CH3COOLi and Mn(CH3COO)2．The XRD showed that the sample exhibited good single-phase spinel．The charge·discharge test showed that the initial capacity ofthe sample reached l 17mAh／g and the sample had better cycling performance．The AC impedance spectrum indicated tha