掺杂对红色长余辉发光材料ca0.8zn0.2tio3;pr3发光性能的影响-doping ca 0.8 zn 0.2 tio 3 to red long afterglow luminescent material; effect of pr3 on luminescent properties.docxVIP

太原理工大学硕士研究生学位论文PREPARATION AND LUMINESCENT PROPERTIES OF RED LONG PERSISTENT+PHOSPHORS CaO.SZnO.2Ti03: Pr3+ABSTRACTConsiderable research attention in the long lasting photoluminescence (LLP) has been shown over the last few years for its potential technologica l application ， such as road signs，graphic arts，interior decoration and autòmobile instrument with high luminous efficiency and so on. Nowadays ，in tricolor，phosphors ofthe green and blue phosphorescence，which have high brightness and goodchem ical stability，can be successfu l1y prepared to meet the demand of all-nightl uminescence ，but the red persistent phosphors 盯e still under the stage of+research. CaTi03: Pr3+is of special interest because it has better chemicalstability and its chromatic coordinates (x = 0.680，y = 0.311) veηclose to ideal+red，however，the decay time of CaTi03: Pr3+is as short as a few minutes andthe initial intensity is very weak，so a great number of efforts have been focusedon the improvement of the fluorescence and phosphorescence of this phosphor by adding different dopants.Firstly，the best miUing time 6h，sintering temperature 1300.C and constant+ll1temperature time 4h were obtained through experìments on CaTiO): Pr3+， Nb+ll1太原理工大学硕士研究生学位论文+in this paper. ln order to improve the luminescence properties of CaTi03:Pr3气 a series of CaTi03: Pr3 ，CaTio97Nbo.0303: Pr3飞 CaoιZnO.2Ti03: Pr3飞 Cao.SZnO.2 Tio.97NbO.0303: Pr3+ and doped-B3+ Cao.sZno.2Tio.97Nb00303: Pr3+ were prepared through conventional solid state reaction method. The results of 由e photoluminescence excitation and emission spectra showed that all the samples emitted red phosphorescence at 612 nm originating 仕om ID2 to 3H4 emission of+Pr3+ under the 337 ruηexcitation. When examined by the X-Ray diffraction (XRD)，a11 the samples presented a predominant phase of CaTi03) except(JCPD#42-42) exceptZn21doped samples which also revealed another phaseof Zn2Ti30S (JCPD#73-579). The results