掺杂聚合物光纤放大器的材料设计 制备及性能分析-material design, preparation and performance analysis of doped polymer optical fiber amplifier.docxVIP

申嚣瓣学拽车夫萼博士孝孽论竞摘要申嚣瓣学拽车夫萼博士孝孽论竞摘要本论文围绕掺杂聚合物光纤材料和聚合物光野放大嚣，主要避抒了以下磅究工雩譬：l对Eu(DBM)3Phen掺杂聚甲基丙烯酸爵熊(PMMA)材料，通过荧党光谱， 避场光学{曩描显微镜和豫稳态寿命结果分析爱踞，材辩中Eu3+离予的微观环境没 有随浓度增加发生明显改变，在意浓度的掺杂撵燕中未发现导致焚光淬灭瞧撼± 离子聚集蕊或函簇存在，这些现象可归露予鏊合凌Eu(DBM)3Phen麴分子结棱。 攫爨袭麓毙赘，篆焉Judd-Ofett鬟谂黠Eu(DBi*f)3．Phen掺杂PMMA耪鹗煞藕嚣 特性谶行了预测，结果表明Eu3+离子的5Do一”?2黥迁有可熊作为激光跃迁用于聚 合秘光纾教丈器。2使鼹Ar+离予激光器在457．9rim处袋濮EufDBM)3Phen掺杂的聚合甥光纤撩±离子掺杂露度4000ppm-wt)，褒褰裂：安大熬妻发骧嚣魏象(ASE)。对于 50era长的掺杂聚合物光纾，ASE泵清静闽傻功率为120mW。对光纾长度的考察 袭硝，50cm是获得最大ASE输国的最佳长曩，箕量子转换激率约40％。使用 YAG激光器在355nm处对长度戈30cm，掺紊浓黢4000ppm．wt嬲掺杂聚台锈光 纾鬃瀵，并蘑613Ima波长鼹竞露为售号是，姿竣入蕊售号光功率轰0。2W，泵灌 懿熬溪密褒为3．02 mJ／ram2衬，褥婺麴蕊弩溪赞为j。7813。对Eu(DBM)3Phen掺 杂的聚合物光纤放大器的数值模拟结果表羽：在i00mW的聚浦功率下， Eu(OBM)3Phen掺杂淤跃麓聚合黪光绥的长浚为80era时，可获褥缀丈为{ldB静 增蕊。3考察了三转第二嚣薅Sm鏊台兹戆菠煮凑凝，茇甏蠹TPPO{乍为第二琵镩 时，对予发光鲍蠛强甏嬲显著。选用Sm(DBN妫(TPPo)2侔为发光介臻掺入 PMMA，利用吸收光谱和发射光谱对蕻麓射特性进行了预测，结聚表明 Sm(DBM)3(TPPO)2掺杂的PMMA可用于铡餐穗±掺杂聚食物光纾敫大嚣；4嚣予掺杂浓度为5ppm-wt靛Rodamine B掺杂泠跃塑聚合铭舞终，卷其长 菠态60em对，荔较为4009in对，在630hm蘩号壳滚长楚，哥获N-23dB戆嘉髦 益，信号光波长更接近PMMA芯聚合物光辨煎通讯窗口。当泵浦光功率为lOkW， 怼予630hm蔷号光波长，渗杂聚合耱竞纾增囊瓣缀佳长凌为60cm。串藏隼}学技末走擘嚣士学住论文ABSTRACT串藏隼}学技末走擘嚣士学住论文ABSTRACTWith the development of polymer optical fiber(POF)，increasing research activities have been also carded out in the field of polymer oVdcal fiber amplifiers．In this thesis，the related research works have been carded out as follows：】Eu(DBM)3Phen doped poly(methyl methacryate)(P1VSMA)with different doping concentration were prepared and their microstructure and optical properties have been investigated by near-field scanning optical microscopy(NSOM)， metastable state lifetime and fluorescence spectra．Concentration quenching was not detected and the local structure and asymmetry in the vicinity of europium ions were not changed．The chemical structure of Eu(DBM)3Phen accounts for all thesephenomena．The Judd·Ofelt parameters，Q 2，Q 4 were obtained from the fluorescenceemission spectra of Eu(DBM)3Phen doped PMIVIA。The evaluation of the radiative properties ofEu(DBM)3Phen doped PMMA showed that it is ofpotential to be a laser matefial at 61