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掺杂氧化铈基极限电流型氧传感器的分析-analysis of cerium oxide doped limiting current oxygen sensor
BZCYYb. The limiting current platform appeared in different oxygen concentrations when voltage was 0.8V-1.7V and temperature was 550℃-750℃. The current maximum value reduced obviously after introducing of electron block material. The limiting currentlinearly increased with the oxygen volume fraction. In addition, the result of oxygen sensitivity test indicated that the current maximun value decreased with the increasing thickness of electron block material, but the voltage platform interval became broaden.The thick film type oxygen sensor with LSCF as diffusion layer, also got stable current plateaus in oxygen concentration from 11% to 20% at 700 ℃. The current maximum value reached 12mA, and as well as there was a linear relationship betweenlimiting current and oxygen concentration. The sensor displayed a good oxygen sensitive performance.Key Words:Oxygen sensor;Dense diffusion barrier;Co-pressing and co-sintering;Screen printing;Electron blockIII目 录摘 要 IAbstract II引 言 11 文献综述 21.1 氧传感器的应用 21.2 氧传感器的类型 31.2.1 氧浓差电池型氧传感器 31.2.2 氧化物半导体型氧传感器 51.2.3 极限电流型氧传感器 51.3 Ce0.8Sm0.2O1.9(SDC)固体电解质基体材料 91.4 固体电子-氧离子混合导体材料 101.4.1 钙钛矿型氧化物混合导体导电机理 111.4.2 钙钛矿型混合导体材料的透氧机理 111.4.3 La1-xSrxCo1-yFeyO3(LSCF) 、LaNi0.6Fe0.4O3(LNF)钙钛矿型氧化物... 121.5 BaZr0.1Ce0.7Y0.1Yb0.1O3-δ 电子阻塞层材料 131.6 选题的目的和意义 132 粉体制备和测试方法 152.1 实验原料及仪器设备 152.1.1 实验原料 152.1.2 实验仪器设备 152.2 氧传感器材料粉体的制备 162.2.1 SDC 固体电解质粉体的制备 162.2.2 致密扩散障碍层 LSCF 和 LNF 粉体的制备 172.2.3 电子阻塞层 BaZr0.1Ce0.7Y0.1Yb0.1O3-δ 材料的制备 182.3 性能测试 192.3.1 粉体的物相分析 192.3.2 显微形貌分析测试 192.3.3 氧传感器电性能测试 192.3.4 氧传感器氧敏性能测试 193 SDC/LNF 共压共烧氧传感器的研究 213.1 氧传感器的材料性能分析 213.1.1 SDC-碳酸盐复合电解质的制备 213.1.2 SDC-碳酸盐复合电解质材料物相分析 213.1.3 LNF 致密扩散障碍层材料物相分析 213.2 SDC/LNF 共压共烧氧传感器的制备 233.3 SDC/LNF 共压共烧法制备氧传感器断面分析 233.4 SDC/LNF 共压共烧氧传感器电化学性能 243.5 共压共烧极限电流型氧传感器氧敏性能 253.5.1 SDC/LNF 氧传感器极限电流与氧体积分数的关系 263.5.2 SDC/LNF 氧传感器极限电流与工作温度的关系 283.6 本章小结 304 SDC/BZCYYb/LNF 共压共烧氧传感器的研究 324.1 BaZr0.1Ce0.7Y0.1Yb0.1O3-δ 电子阻塞层材料物相分析
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