掺杂钴铁氧体coxfe3xo4纳米微晶结构与磁性研究-study on microstructure and magnetism of cobalt-doped ferrite co xf e3 xo4 nano - crystallites.docxVIP

第一章磁光效应与磁光记录材料关键词：第一章磁光效应与磁光记录材料关键词： 钴铁氧体：磁光记录材料；掺杂；溶胶．凝胶法H掺杂钴铁氧体Co。Fe3．。04微晶结构与磁性能研究Abstract掺杂钴铁氧体Co。Fe3．。04微晶结构与磁性能研究AbstractResearch on magneto-optical storage is a very important branch in the field of magnetic information memory．The development of magneto-optical recordingtechnology and materials is much sigllificance for the progress of high capacity,density and erasable information recording technology．As the first generation magneto-optical recording material，TbFeCo has partly met the demands of market, but the antioxidation susceptibility of the rare-transitional subgroup elements is verypoor,so it is a incipient fault for the information that inquire permanent preservation,besides，this material has limited the recording density for it can’t work in the range of short wavelength，Therefore，it is urgent to explore the new generation of short-wavelength magneto—optical recording materials．Cobalt ferrite has been considered as attractive candidates for magneto·optieal recording materials because of the good magnetic properties，chemical properties and Kerr effect in the range of400-500rim wavelength．In this thesis，cobalt ferrites COxFe3．x04(x=O．2—1．0)and Cr substituted nanoerystalline powders werc prepared by chemical coprecipitation route．The powder samples were characterized by x—ray diffractometry(XRD)and vibratingsample magnetometry fvSM)．We discussed the structure and magnetic properties ofthe samples．The main results were as follows：1．Structure phase transition and magnetic properties of the CoxFe3．x04 were studied systematically．The experiment results show that the cobalt content has great influence on the sample structure，Monophase with a spinel structure were formed at high C02+content(埏O．7)，while at the lower C02+content(x0．7)，CoxFe3．x04phaseand 0L-Fe203 phase were obtained at the same time．The specific saturation magnetization Can be improved by properly increasing the cobalt content,2．Magnetic properties call be improved by properly reducing c