不同c n比低浓度污水的a o n脱氮研究-study on a o n nitrogen removal from low concentration sewage with different c n ratios.docxVIP

摘 要 传统脱氮理论认为：在低浓度污水生物脱氮过程中，进水 C/N 比过高，自养硝 化菌在大量有机物存在的条件下，对氧气和营养物的竞争不如好氧异养菌，从而导 致异养菌占优势，使得氨氮不能很好地转化为亚硝酸盐或硝酸盐，以致降低硝化反 应速率；进水 C/N 过低，硝化反应时间过长，反硝化过程缺乏足够的有机物作为电 子供体，导致反硝化效率低。据此，本文进行了不同 C/N 比下低浓度污水的 A/O/N 工艺脱氮试验研究。试验结果表明，由于 A/O/N 工艺将异养菌和自养硝化菌分别置 于两个反应器中，使其在各自适宜的环境中生存，两者之间不存在竞争问题，硝化 率效果不受进水 C/N 比的影响，进水 C/N 比为 5.1 时脱氮效果最佳，继续增大进水 C/N 比，硝化率响；在 A/O/N 工艺中，当进水 C/N 比在 2.2-9.8 之间变化时，TN 去 除率随 C/N 比呈规律性变化。 A/O/N 工艺和 A/O 工艺的对比研究结果表明：在进水 C/N 比偏低条件下，A/O/N 工艺的脱氮效果明显优于 A/O 工艺；A/O 工艺最佳进水 COD/TN 比为 7.7，且其硝 化率随着 C/N 比的增大而减小，之间呈良好的线性关系；A/O/N 工艺硝化效果不受 进水 C/N 比的影响，在 C/N 比很高的情况下，A/O/N 工艺系统硝化率仍高达 95%。 对 A/O/N 工艺脱氮机理的研究表明，A/O/N 工艺脱氮过程中发生了短程硝化反 硝化反应；文中就短程这一特征的反硝化动力学模式进行了初步探讨。 关键词：低浓度污水;A/O/N 工艺;C/N 比;短程硝化反硝化  Abstract According to traditional denitrification theory, while influent C/N ratio is much too high in biological nitrogen removal process, autotrophic organism under the existence of a lot of organic substance is less competitive than heterotrophic bacteria in the scrambling for oxygen and nutrition, which makes heterotrophic bacteria in the ascendant and ammonia not translated into nitrite and nitrate very well , so that denitrification efficiency reduces; if influent C/N ratio is too low and nitration reaction time lasts too long, this may cause low denitrification efficiency because of lacking of enough organic substance as electron offerings. Hereby, the experimental investigation on A/O/N process was done for wastewater with low concentration and different C/N ratio. The results show that thanks to their living in respective fitting environment in separate reactors, there is no the competition between heterotrophic bacteria and autotrophic nitrate bacteria, the nitration efficiency was not influenced by influent C/N ratio, the best nitration can be obtained when influent C/N ratio is 5.1, and nitration efficiency and denitrification efficiency cannot be influenced by the increasing C/N ratio; in the A/O/N process, when influent C/N ratio is between 2.2 and 9.8, the TN removal efficien