变质粮食热分解特性分析-analysis of thermal decomposition characteristics of deteriorated grain.docxVIP

TG curves under different metamorphic grade, and the trend is basically similar. While metamorphic grain at different heating velocities for the linear temperature thermal decomposition experiments, the TG curve sharps are similar. Metamorphic sample thermal decomposition is mainly concentrated at 260 ℃- 380 ℃, and reaches the maximum about 300 ℃. With the heating rate increasing, weight loss and weight loss velocity curve of the samples both move to the high temperature zone, and the thermal decomposition velocity increased, so did the characteristic temperature, including thermal decomposition initial temperature, weight loss peak value temperature and thermal decomposition terminate temperature. Analyzing thermal decomposition process of metamorphic grain by Coats-Redfern method and choosing the n value as 1, 1.5 and 2 respectively, thermal decomposition kinetic model of metamorphic grain was set up. Studying the thermal decomposition process from the dynamic viewpoint, thermal decomposition kinetic expressions of metamorphic grain were built. Finally, the reaction kinetic parameters, activation energy E and pre-exponential frequency factor A at different experimental conditions were calculated. Under different thermal decomposition conditions, the reaction kinetic parameters are different and activation energy increases with the increasing of heating velocity as well as the frequency factor. The experimental results indicate that the experiment has preferable linear fitting results.And the linear regression equations of three metamorphic grade were also gained. When the heating velocity is low, choosing the n value as 1 has a preferable linear fitting result; while the heating velocity attained 20 ℃/min, n value as 2 is better. Keywords：metamorphic grain；thermal decomposition；TGA；kinetic 学位论文独创性声 明 本人郑重声明： 1、坚持以 “求实、创新 ”的科学精神从事研究工作。 2、本论文是我个人在导师指导下进 行的研究工作和取得的研究 成果。 3、本论文中除引文外 ，所有实验 、数据和有关材料均是真实的。 4 、本论文中除引文和致谢的内容外，不包含其他人或其它机构 已经发表或撰写过的研究成果。 5 、其他同志对本研究所做