共振光散射光谱分析及在三元离子缔合体系中的分析应用-analysis of resonance light scattering spectrum and its application in ternary ion association system.docxVIP

共振光散射光谱研究及在三元离子缔合体系中的分析应用曾文共振光散射光谱研究及在三元离子缔合体系中的分析应用曾文IVIVparticles by virtue of hydrophobic forces and other molecular forces. It’s found the RLS intensity of the system has significant enhancement at 334nm, and the enhanced intensity of RLS is proportional to the concentration of Zn2+ .The linear range is 64ug/L-1920ug/L with a correlation coefficient of 0.9989.The detection limit is 0.62ug/L.Thus a new analytical method for determination of Zn2+ has been established. It has been applied to the determination of Zn2+ in power milks with satisfactory results.We have studied mechanism and influence factors of resonance light scattering spectra of fluorescein(Flu) in detail. In neutral and alkaline solutions, the RLS intensity of Flu is enhanced significantly. It’s found that the RLS, fluorescence and absorption spectra are the same tendency on intensity and the change of wavelength with the increase in pH. The fluorescence excitation and emission spectra of Flu overlap partly, and the RLS peak lies between the fluorescence and emission peaks. In light polarization experiment, the polarization of Flu is measured to be P≈0.020.We also investigate the changes of RLS spectra and fluorescence spectra when the concentration of Flu solution increases in strong alkaline solution. It also indicates the two spectra are connected closely. All the above experimental facts reveal that the RLS of Flu is resonance fluorescence.Mechanism and influence factors of resonance light scattering spectra of crystal violet (CV) aqueous solution are studied. The intensity of RLS of CV increases with an increase in pH before pH =11.It comes to the strongest when the pH =11.Then it keeps steady. Acidity of the solutions influences the acid-base equilibrium of CV and its existing state. The inherence result of the enhance of RLS is the forming of molecule congeries. We also find the spectral feature of RLS is related to the absorption spectra of CV. By a light polarization experiment, the RLS of