纳米tio2pvdf-hfp微孔膜的制备与性能研究-preparation and properties of nano tio _ 2 pvdf - hfp microporous membrane.docxVIP

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2018-07-27 发布于上海
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纳米tio2pvdf-hfp微孔膜的制备与性能研究-preparation and properties of nano tio _ 2 pvdf - hfp microporous membrane.docx

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纳米tio2pvdf-hfp微孔膜的制备与性能研究-preparation and properties of nano tio _ 2 pvdf - hfp microporous membrane

SynthesisandpropertiesofNano-TiO2/PVDF-HFPmicroporousmemebraneAbstractInthecomponentsofthelithium-ionbattery,themembraneplayedanimportantimpactontheperformanceofthelithium-ionbattery.Thepolyvinylidenefluoride-hexafluoro-propylene(PVDF-HFP)canprovidehighdielectricconstant,goodheatresistance,chemicalcorrosionresistance,electrochemicalproperties,whichissuitableforlithium-ionbatteryseparatormaterial.Butithasshortcomingsofthefilmisbrittle,poortoughness,highcrystallinity,whichlimitingtheapplicationinthemembranematerial.Inordertoresolvetheproblemoflowliquidabsorbent,poormechanicalpropertiesandlowerheatresistance,weimprovedtheperformanceofmembranematerialusingmethylmethacrylate(MMA),polyethleneglycoldimethacrylate(PEGDMA),N-methyl-pyrrolidone(NMP),nanoTiO2.Weresearchedtheperformanceofthemembranepreparedbynano-TiO2/PVDF-HFP.Theanalysisshowedthattheoptimumconsistenceofthesolutionwas5%,theoptimumtemperatureis70℃whichwasneededbypolymerizationbuiltchainandnetworkstructureofMMAandPEGDMA,andtheoptimumtimeofpolymerizationis6hours.AndthesinglefactoranalysisshowedthattheoptimummolrateofPVDF-HFP,MMA,PEGDMAwas8:4:1,andmessrateofNMPandPVDF-HFPwas2:1.TheliquidabsorbingrateanalysisshowedthatwhentheTiO2masspercentagewas15%,themembranegotthehighestliquidabsorbingrate,reachedto190%morethantheothercondition.TheanalysisofmechanicalbehaviorshowedthatthetensionrosefirstlyandthenreducedgraduallyasincreasingthemassrateofTiO2inPVDF-HFP,andwefoundtheoptimummechanicalperformancewhenmassratewas15%.TheanalysisofTGshowedthatitsdecomposingtemperatureupto250℃whenthemassrateofTiO2inPVDF-HFP,whichcouldachievethedemandofthermalpropertyinlithiumbatteryseparator.Theanalysisoficonicconductionshowedthattheiconicconductionwasequaledto5×10-4S·cm-1whenthemassrateofTiO2inPVDF-HFPwas5%,10%and15%.Keywords:Lithium-ionbattery,Polyvinylidenefluoride-hexafluoropropylene,NanoTiO2,Membrane,Polymermodification目录1概述1.1引言··························································································11.1.1电池的发展概况及应用·