耐高温透红外alon陶瓷的制备及性能分析-preparation and properties analysis of high temperature resistant infrared - transparent alon ceramics.docxVIP

3.1实验原料的表征.......................................................................................264.2.5试样抛光前后的显微结构..............................................................584.2.6热压烧结光学性能分析..................................................................594.3本章小结....................................................................................................61第II页第五章结论..........................................................................................................62致谢......................................................................................................................64参考文献..................................................................................................................65作者在学期间取得的学术成果.............................................................................71表目录表1.1主要的中红外窗口无机材料..............................................................................3表1.2三种主要的耐高温透中红外材料的性能对比..................................................4表1.3AlN-Al2O3伪二元系中的氮氧化铝相8表3.1AlON粉末中各元素的含量33表4.1不同球磨时间的AlON粉末的粒径分析50表4.2不同烧结时间对AlON陶瓷力学性能的影响57表4.3不同压力对AlON陶瓷力学性能的影响58图目录图1.1典型的红外精确制导导弹（a）巨人导弹（b）米卡导弹1图1.2AlON光学陶瓷制品6图1.3Surmet公司AlON陶瓷的透光率6图1.4AlN-Al2O3伪二元相图7图1.5透明材料的透过率与波长的关系.....................................................................15图1.6双原子分子的振动模型.....................................................................................16图1.7Ge(1.115mm厚)不同温度下的透过率17图1.8蓝宝石在不同温度下的透过率........................................................................17图1.9陶瓷内光波散射示意图....................................................................................18图2.1本文的研究方案及实验过程示意图................................................................21图2.2陶瓷弯曲强度测试示意图................................................................................24图3.1γ-Al2O3粉末的XRD图谱26图3.2γ-Al2O3粉末与α-Al2O3粉末的XRD图谱对比27图3.3AlN粉末的XRD图谱27图3.4γ-Al2O3粉末的形貌（(a)SEM，(b)TEM）28图3.5AlN粉末的形貌（(a)SEM，(b)TEM）29图3.6γ-Al2O3与AlN粉末混合后的TEM照片29图3.7不同温度下保温3h后的粉末的XRD图谱（30mol%AlN）30图3.8Rietvel