球磨及催化剂对mg2-xndxnix=0.1-0.4贮氢合金电化学性能的影响-effect of ball milling and catalyst on electrochemical properties of mg2 - xnd xnix = 0.1 - 0.4 hydrogen storage alloy.docxVIP
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球磨及催化剂对mg2-xndxnix=0.1-0.4贮氢合金电化学性能的影响-effect of ball milling and catalyst on electrochemical properties of mg2 - xnd xnix = 0.1 - 0.4 hydrogen storage alloy
T=72hhasshowthegoodkineticsperformance.Whenx=0.3and0.4,theas-castalloyhasthebestkineticsperformance.Thephasestructureofalloyhasn’tchangedbyaddingcatalystFeindifferentmillingtime,however,theFeincreasetheamorphizationprocessofalloy.ThemaximumdischargecapacityofMg2-xNdxNi(x=0.1,0.2)alloyincreasedbyaddingcatalystFein24hmillingtime.ThecapacityretentionrateofthisalloyimprovedbyaddingFein72h.ForMg2-xNdxNi(x=0.3,0.4)alloywithdifferentmillingtime,thecatalystFeenhanceditscapacityretentionrate.AppropriatemillingtimetoaddcatalystFeplayedapositiveroleinthekineticsperformanceofalloywithdifferentNdcontent.KeyWords:Ndelementsubsitution;Ballmilling;CatalystFe;hydrogenstorageperformance目录摘要....................................................................................................................................IAbstract..................................................................................................................................II1文献综述..........................................................................................................................-1-1.1储氢合金的发展概况材料发展概况.................................................................-1-1.2Ni/MH电池简介...................................................................................................-2-1.2.1Ni/MH电池的工作原理...........................................................................-2-1.2.2贮氢合金在Ni/MH电池中的发展.........................................................-3-1.3贮氢合金的类型及发展现状.............................................................................-5-1.3.1AB5型贮氢合金.........................................................................................-5-1.3.2AB2型Laves相贮氢合金........................................................................-6-1.3.3A2B镁基储氢合金....................................................................................-6-1.3.4AB型钛铁系储氢合金.............................................................................-7-1.3.5V基固溶体型贮氢合金...................................
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